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By Martin G. Wafforn, George J. Greer

"In early 2014, Pan American Silver Corp. commenced a project to construct a second shaft at its La Colorada underground mine located in Zacatecas State in Mexico. This was the first new shaft development project undertaken by Pan American Silver in the history of the company. The existing mine workings permitted the use of a raise bore for the excavation of the shaft opening, utilizing directional drilling in poor ground conditions to advance the pilot hole. This was an interesting project with many challenges and successes, and numerous lessons learned. The project was successfully completed in 2016, with the shaft operating at full mine production capacity within weeks. INTRODUCTION The La Colorada Mine has a long history dating from at least the 1920’s. The mine is located in the northern portion of Zacatecas State in Mexico in the Chalchihuites area, an approximate two hour drive south from the city of Durango. Pan American Silver acquired the La Colorada mining concessions in 1998, with mine production at that time consisting of only a few hundred tonnes per day. Over the course of the following 15 years, with the addition of an oxide processing plant and some expansions to the sulphide processing plant and site infrastructure, production was eventually increased to a maximum of 1,250 tonnes per day, all of it generated from conventional cut-and-fill stopes in the underground mine. An existing shaft was used to hoist the ore to surface, and over the years Pan American Silver had deepened the shaft and had changed out some of the hoisting plant. However, there were historic workings in close proximity to the shaft that made it unsuitable for personnel transport, and shaft maintenance was becoming difficult. The shaft was increasingly considered as a risk to the long term production continuity, and also to further deepening of the mine. In addition, expanding the capacity of this old shaft was not possible. Drilling of the La Colorada mineralization at depth commenced in 2010, with very good exploration success. As a result, by the end of 2013, the mine reserves had grown to a total of 6.5 million tonnes of high grade ore (388 g/t Ag, 0.36 g/t Au, 2.4 % Zn, and 1.3% Pb). Furthermore there were more (and higher grade) sulphide reserves than oxide reserves at depth. Following the completion of an internal study in 2013 with assistance from one of the international shaft contractors, a decision was made to increase the production from the mine with the construction of a new shaft and a new sulphide processing plant, a project with a calculated payback of 2.2 years."

Jan 1, 2019

By Joey Hoang, Robert Johansson, Tapani Keronen, Mikael Jåfs, Jani Jansson, Mikko Korpi

At the Copper 2016 conference in Kobe, Japan, Outotec introduced a vision for the year 2020, wherein smelting would make use of four digital cornerstones: intelligent instruments, advanced process control, improved information management and transparency of and access to data. Since then, this vision coined the phrase “Fully Automated Smelter” with the mission promising a concept where no manual actions from human operators would be needed during normal smelter operations. Replacing repetitive physical work, collection and analysis of everyday production data has a great potential for further automation and will provide productive ways to improve efficiency and safety of smelters in the future. Therefore, a lot of emphasis has been put into developing solutions to automate these tasks and to move people out of harm’s way. A lot of new equipment, systems and optimization tools are under development. In addition, a lot of effort is going into developing dynamic process models and advanced control systems to interface with the plant automation systems. The goal is to integrate all these concepts to meet Outotec’s Fully Automated Smelter vision. This paper will cover these latest achievements toward this vision and introduce the near-future of digital smelting. INTRODUCTION As is well known already, the humankind is currently experiencing a change, extent of which is broadly studied by the governmental, educational and industrial institutions and parties. The wellbeing and quality of life have traditionally been improved alongside the developments in industrial production, which is now about to enter its fourth revolution. Therefore, the current change is often described as fourth industrial revolution, or industry 4.0 (or industrie 4.0, as named by Acatech, 2013) and can be considered anything from small incremental development to a ground-breaking global reset that will affect everyone’s lives. Many seem to agree, that the scale of change will indeed be big, even significantly bigger than the three industrial revolutions before it (Pellini, Weyrauch, Malho & Carden, 2019; Geissbauer, Vedso & Schrauf, 2016; Jansson, Bjorklund, Lahtinen, Heinonen, Jafs & Fagerlund, 2016).

Jan 1, 2019

By D. Tetsuka, H. Okamoto

The amount of impurities to be processed in a copper smelting process has increased for recent years because of an increase in the electronic scrap amount. It has been found that Sb and Ni effect on the operation of our copper electrorefining process. It is found that the current efficiency of the copper electrorefining tended to be decreased as the Ni concentration in the electrolyte increased. The passivation of the process seemed to be more related to SO4 concentration in the electrolyte rather than the Ni concentration in it. The current efficiency decreased when the Sb content in the anode was high. A high Sb content in the anode caused easy passivation by forming a gel-like film in the slime layer. We have developed a method to for see the anode passivation in a short time while generating a slime layer. We confirmed the tendency of passivation through the experiment of changing Pb content in anode. Passivation was easily occur with an increase in Pb content in the anode. The amount of slime increased as the Pb content in the anode increased. This suggests that passivation was facilitated because liquid diffusion near the anode was inhibited. INTRODUCTION The amount of impurities to be processed in copper smelting has been growing in recent years because the amount of electronic scrap has increased. Figure 1 shows that the contents of Sb and Ni in copper anodes have increased since 2007.High Sb and Ni contents in the copper anode decreased the current efficiency of the process and made the quality of copper cathode poor because of the anode passivation and the formation of floating slime in the electrolyte during electrorefining. If these influences of impurities are suppressed, it would be possible to make copper electro-refining current density higher and to process much amount of electronic scrap. We examined the components of our copper electro-refining process like anode composition, slime properties and electrolyte composition, and investigated the mechanism by which Sb and Ni affect passivation and current efficiency. When examining the influence of Ni, we noticed that the SO4 important. The effect of SO42 – was also discussed

Jan 1, 2019

By J. Gustavsson, S. Holmin, Å. Afvander, E. Rosseland, E. Zimmerman

There are numerous advantages in replacing lead-based anodes with mixed metal oxide (MMO) coated anodes in copper electrowinning; for example, lower energy consumption, improved working conditions for operators and less environmental impact. Since 2012, Permascand AB in Ljungaverk, Sweden has evaluated Permascand coated titanium anodes in copper electrowinning pilot trials at Glencore Nikkelverk in Kristiansand, Norway. The investigation has proceeded in three different steps (Phase I, II and III). In Phase I, different Permascand coatings, electrode structures and coating methods were investigated. The results showed that improved current distribution, lower energy consumption and longer service life could be obtained with expanded mesh electrode structure in a box configuration compared to rod anodes in a single-mode construction. In addition, improved current distribution and less coating wear was found when electrostatic spray coating was used instead of brush (manual) coating. It was also found that the extrapolated service life from controlled lab experiments at 200 A/m2 was much shorter compared to what was experimentally obtained in copper electrowinning pilot trials at similar current densities. This was mainly attributed to different coating failure mechanisms in lab and industrial copper production. INTRODUCTION Traditionally lead-based anodes have been used in copper in electrowinning due to lower cost. But there are many advantages in replacing lead-based anodes with mixed metal oxide (MMO) coated titanium anodes in copper electrowinning, such as lower energy consumption, higher corrosion resistance, improved working conditions for operators and less environmental impact. Still, many facilities are using lead-based anodes, although the progression of using metal oxide coated anodes in copper electrowinning has slightly increased (Robinson et al., 2012).

Jan 1, 2019

By Avi Nanda, Robert Brandt, Alex Piatkiewicz, David M. Jones

In 2010 the United States Environmental Protection Agency (UESPA) revised the National Ambient Air Quality Standards (NAAQS) by lowering the permissible value to a 1-hour average SO2 concentration of 75 ppb. In 2012, the USEPA designated the Miami area as non-attaining for the new SO2 NAAQS. A number of options were studied to assist in bringing the Miami smelter into attainment with the new standard. The chosen solution included: Installation of a large tertiary hooding system over the converter aisle; Hooding of the anode vessels and treatment of the anode gas in a baghouse; Installation of a large 2,325,212 Nm3/hr caustic scrubber to treat the captured converter fugitives and anode off-gases; Installation of a secondary ESP for the tapping fugitive off-gas treatment system; and the continuous scrubbing of all acid plant tail stack gases. The modifications have reduced smelter SO2 emissions by 85%, achieving a world class SO2 stack emissions rate of 0.45 kg of SO2/tonne Cu. INTRODUCTION The Freeport McMoRan Miami smelter has been previously described in literature (Steinborn, Pasca, Sallee, Binegar, Bhappu). For the sake of brevity a brief description is given here. The Miami smelter is located 129 km east of Phoenix, Arizona near the town of Miami, Arizona. The smelter was established in 1915 and has undergone a number of process upgrades and modernizations over the years. The present smelter consists of an Isasmelt furnace, an electric settling furnace, four Hoboken converters, two anode refining vessels & one casting wheel; and one double contact sulfuric acid plant. Concentrates are railed & trucked to Miami from four Freeport McMoRan mines located in Arizona & New Mexico. The wet concentrates, typically containing 10% H2O with a Cu/S ratio of 0.85, are smelted in an Isasmelt furnace to a matte grade of 58%. The entire output from the Isasmelt is laundered into an Elkem electric furnace (originally installed in 1972 as the primary smelting furnace) for separation into matte and slag. Slag containing 0.85% Cu is skimmed from the electric furnace and discarded. Molten matte, containing 60% Cu, is tapped from the electric furnace and processed in one of four Hoboken converters to produce blister copper. Two anode refining vessels further refine the blister copper before the final product is cast on a single, 30 mold, casting wheel. All of the anodes produced at Miami are shipped to the Freeport McMoRan electrolytic refinery in El Paso Texas for refining into cathode copper. Smelter off-gases from the Isasmelt, electric furnace and Hoboken converters are combined and treated in a double contact acid plant to produce sulfuric acid. Acid produced at Miami is internally consumed at Freeport McMoRan mines in the region.

Jan 1, 2019

By M. Sommerfeld, U. Schwarz-Schampera, B. Friedrich, D. Friedmann

The steadily growing demand for metals and their price increase at metal exchanges make the mining and utilization of marine mineral resources like polymetallic nodules, manganese crusts or sulfide deposits in the near future a viable option to potentially increase the supply of base and precious metals. For a country with low potential to mine land-based resources like Germany, the industrial recovery of metals from marine mineral resources could lead to a decreased dependency on imports. In this study, seafloor massive sulfides from the German license area in the Indian Ocean (Kairei field, Southern Central Indian Ridge) are treated to recover copper and precious metals. The aim of the project is to demonstrate the transferability of existing metallurgical techniques to the raw material of deep-sea massive sulfides. As a starting point to process this unconventional resource, samples from the Indian Ocean are chemically analyzed and mineralogical characterized. A comparison is carried out between the samples and land-based copper resources, to highlight the potential which lies in mining the deep-sea floor. This paper will show the general possibility of applying a two-stage pyrometallurgical process, based on a concentrate smelting operation, followed by a converting operation in lab-scale to the provided samples of massive sulfides. Generated slag from the concentrate smelting and the converting operation are investigated by X-ray diffraction to determine the mineralogical composition. The two-stage pyrometallurgical process is investigated by the thermochemical modelling tool FactSageTM 7.2 to evaluate the phase distribution of relevant elements between the metal, matte, slag and gas phase. The thermochemical boundaries of the pyrometallurgical process are therefore set and the results of the thermochemical study can be used as an indicator for the efficiency of an up-scaled process and the generated amount of side-streams, which need to be further treated or circulated back into the process. INTRODUCTION Seafloor massive sulfides (SMS) are the third kind of discovered deep-sea minerals besides ferromanganese nodules and cobalt-rich ferromanganese crusts (Sharma, 2017). They occur in water depths around 250–4,000 m (Koschinsky et al., 2018). SMS are characterized by a high base metal and sulfide content. They were created by fluid circulation and hydrothermal convection over time (Han et al., 2018). Commonly, areas rich in SMS are associated with hydrothermal vent fields on the seafloor (Keith et al., 2018).

Jan 1, 2019

By William M. (Bill) Shaver

"The author will review the early history of shaft sinking as well as focus on the improvements made in shaft design and construction over the last fifty years (1970 to 2019) to predict how shaft sinking will change over the next fifty years and describe what the shaft sinking world might look like in 2070. INTRODUCTION It is a great honour to be one of your keynote speakers for the Fourth International Conference on Shaft Design and Construction being held in Toronto in November 2019. This is one of the opportunities we have to thank the Mining Companies of the world as well as the industries and companies we serve for their support of the mining contracting and shaft sinking business of Canada and the world at large. Many of these companies are represented here today. Without your support many of the innovations we will talk about today would not be possible. We would also like to thank all the companies that work with us in our business including all the contractors and suppliers who provide the various services we require. These include equipment manufacturers, engineering companies, project management companies and suppliers large and small who cater to our every need as quickly as possible. Without all these partners we would not be as good as we are. Many of these companies are our sponsors this week. Thank you from all of us! This is also an appropriate time to pause and think about those Shaft Sinkers we have lost and those who have been injured on our projects around the world. Please bow your head and remember the Shaft Sinkers you have worked with, who did not return home or those who returned home injured. Think about how we can continue the work of making shafts safer every day as we go forward with our projects so everyone goes home to their families safe and sound. Pause for a minute and thank you. The subject matter we have chosen to discuss today is “Shaft Sinking in the Next Five Decades”. How will the work be done, how fast will it be done, what will it cost, and why we think this may occur? It is appropriate to consider this over the next few days with this auspicious group we have assembled. Today, we will look back at all the advances that have been made over the last many years and look ahead to the future to attempt to predict what shaft sinking will look like in 2070. When I look around the room I recognize that many of us will not be around then so we need not worry about being wrong. Suffice it to say that the next 50 years will be very interesting and exciting for the shaft sinking business."

Jan 1, 2019

By A. Mazhary, T. Huff

Sensor-based ore sorting technology is a growing area of interest due to lower-grade ore deposits and higher costs of processing, among other reasons. Among the sensors currently utilized in the particle sorting industry, X-Ray Fluorescence (XRF), as the only sensor with elemental analysis capabilities, has always attracted more attention. Currently, the bench-scale amenability tests for this sensor are performed using hand-held XRF analysers. However, this testing method overestimates the performance of the XRF sorter, and therefore, the results from these tests can be misleading and are often mispresented. The work presented here was conducted on a copper mine and investigates how the sensor’s sensitivity to copper deteriorates under different testing methods. This work compares and correlates the results of an Olympus hand-held XRF analyser, static, and dynamic sorter responses with the actual grades of the rocks. The results confirmed that, the sorter response was extremely prone to blind spots. Furthermore, the results demonstrated that although the static sorter’s responses were comparable in terms of rock identification to those of the hand-held XRF analyzer and assays, the accuracy of the dynamic sorter response deteriorated both as a function of grade of the rocks as well as the potential for blind spots. INTRODUCTION Sensor-based sorting technology has been gaining increasing attention even by larger mining corporations as ore grades decrease, deposits get deeper and therefore cost of mining and processing increases. There are various types of sensors that are currently being used in the particle sorting industry such as X-Ray Transmission (XRT), Color, Electromagnetic (EM), Near-Infrared (NIR) and others. However, none of the sensors are capable of identifying and quantifying particles by the elemental content, except for X-Ray Fluorescence (XRF). XRF is a non-destructive, surficial analytical technique used to measure elemental composition of materials. X-ray fluorescence happens when a secondary x-ray (fluorescence) is released after a sample is bombarded by a primary x-ray source. From a sorting perspective, the most common and expected issues that are associated with XRF sorting are lower throughputs compared to other sensors due to particle presentation limitation as well as the need to wash the material before introducing to the sorter. However, one important issue that is mostly neglected is how the amenability tests are performed and how realistic the obtained results are. Current amenability test procedure utilises a handheld XRF analyser (such as an Olympus InnovX, as used in this work) on multiple, generally 4, sides of the rock and uses the average measured grade as a criterion for separation. While this is a widely accepted technique, it fails to consider some important factors such as exposure time and the distance between the sensor and the particle. These factors can significantly affect the sorting outcome.

Jan 1, 2019

By A. Roca, G. Ríos, I. Ruíz, M. Cruells

Flash Smelting Furnace (FSF) hot dust-laden is cooled in a waste heat boiler (WHB) and then dedusted in electrostatic precipitators (ESP’s) before being treated, together with the Peirce Smith Converters off-gases, in the sulfuric acid plants for SO2 removal. FSF dust is sulfated by SO2 and O2 in the WHB. Typically, 70% of the dust from the FSF drops in the WHB while the remainder is caught in the ESPs. The collected dust is recycled to the FSF for Cu recovery. Some smelters have developed hydrometallurgical treatments to recover Cu from the dust; impurities, such as As and Bi, are bled as leach plant residues. This paper presents a study (laboratory scale), of leaching the FSF dust, generated in Atlantic Copper Smelter using the weak acid bleed from the gas scrubbing/cooling section (GSCS) of sulfuric acid plants. Leaching was performed with 0.5 mol L-1 sulfuric acid concentration, 60ºC, and a solid/liquid ratio 1/3. After leaching, H2O2 was used for arsenic and iron oxidation. pH was adjusted for precipitation of arsenic and iron as scorodite or as scorodite and arsenical jarosite. The precipitation was carried out at 95ºC during 3-6 h. Liquids after precipitation are suitable for subsequent treatments of electrolysis. INTRODUCTION The copper smelter dusts are usually recirculated totally or partially to the flash furnace. This practice increases the amount of impurities feeding the furnace. Some authors have developed processes for treatment of these materials for copper and zinc recovery and for arsenic, antimony and bismuth inertization. The processes for the treatment of copper smelter dusts can be pyrometallurgical (Yu, 1987; Carter, Vance, Aldridge, Zaw, & Khoe, 1994; Fu, Jiang &Wang, 2000), hydrometallurgical, or mixed processes (Yin et al, 1992; Mulale, Mwema, & Mashala, 1999; Gorai, Jana, & Khan, 2002). Hydrometallurgical processes have been extensively studied and, in some cases, applied to an industrial scale. The most important chemical reagent proposed for leaching the dusts has been sulfuric acid (Roman-Moguel, Plascencia, Pérez, & Garcia, 1995; Gabb, & Evans, 1997; Larouche, 2001; Morales, Cruells, Roca, & Bergó, 2010; Cáceres, Cruells, Morales, & Roca, 2012; Ecometales, 2013; Yang, Fu, Liu, Chen, & Zhang, 2017). Processes developed in alkaline media, and in some cases with the presence of sulfide, have also been carried out (Gabler, & Jones, 1988; Morales, Hevia, & Cifuentes, 2009; Alguacil, Garcia-Diaz, Lopez, Rodriguez, & Alonso, 2013), as well as by using a bioleaching process (Massinaie, Oliazadeh, & Seyed Bagheri, 2006; Bakhtiari, Atashi, Zivdar, Seyedbagheri, & Fazaelipoor, 2011).

Jan 1, 2019

By Wataru Inagaki, Kozo Kawano, Tetsuya Ando

Cu–Ni–P alloys are the typical precipitation-hardening material. Thus, Cu–Ni–P alloys is expected to apply alternative materials for heat-exchanger tubes. Therefore, it was investigated that the effect of the heat-treatment simulated brazing on mechanical properties of Cu–Ni–P alloy in this study. The hardness of specimen as heat-treatment simulated brazing after solution heat treated (sht) was shown approximately 105 HV. The peak hardness and tensile strength of the specimen as performed aged at 498 K for 43.2 ks following the heat-treatment simulated brazing achieved at approximately 140 HV and 260 MPa, respectively. From these results, it is expected the application to higher-strength tube for heat-exchanger after brazing in a furnace. INTRODUCTION Copper prices have increased dramatically with high in recent years. At the same time, manufacturing industries are required to reduce the environment load by reducing the wall thickness of the copper tubes used in heat exchangers. High-strength copper alloys are developed for reducing the wall thickness, while achieving high strength, of the copper tubes. Moreover, excellent workability and corrosive durability are also required by these copper tubes. Furthermore, the brazing, which are carried out at about 1050 K during the assembly process of heat exchangers, leads to grain growth and re-solving of additive elements. Nomura et al. achieved a tensile strength and Vickers hardness of approximately 260 MPa and 110 HV, respectively, after aging at 723 K for approximately 36 ks. Tamagawa et al. studied that the strength of Cu–Ni–P alloy rapidly increased at about 125 HV during the cooling process after the heat brazing due to the Ni2P precipitates sized 5–10 nm. Furthermore, Inagaki et al. achieved a Vickers hardness of approximately 130 HV by aging at 498 K for 10.8 ks. In the present study, we focused on the lowest aging temperature of 498 K in the previous study, and investigating the effect of heat-treatment simulated brazing on the mechanical properties of the Cu–0.93 mass%Ni–0.24 mass%P alloy.

Jan 1, 2019

By A. Pearson, F. A. Auld, S. O. Colbeck

"""The theory of buckling of shafts and Steel tunnel-linings"" was published by E. Amstutz in 1970 and commented on by S. Jacobsen in 1974. The authors have revised and enhanced Amstutz’s work to address Jacobsen's comments on its limitations and to extend its validity over a wider range of pipe/shaft geometries, including those commonly found in deep mine access shafts. The author has looked at Amstutz’s assessment of strengthening with flexible shear anchorages and adapted the theory of non-linear shear deformation response of bolts to develop a method of assessing increased buckling capacity utilising the full plastic shear capacity of studs. INTRODUCTION “Amstutz Buckling” refers to the buckling of pipe embedded in concrete under external uniform pressure. In terms of a mining environment, this relates directly to the design of a watertight shaft. This load case will commonly occur where a main shaft is cast against a geostatically stable primary liner and the only load applied to the final shaft is that of a uniform ground water load. Ernst Amstutz wrote his first paper on buckling of pressure-shaft steel linings in 1950 and subsequently improved his theory (Amstutz, 1970), which was then widely adopted for use within the industry. Years later, an alternative approach (Jacobsen, 1974) was proposed. Within his paper Jacobsen critiques Amstutz work, identifying some mathematical inconsistencies and highlighting limitations of the theory imposed by approximations adopted by Amstutz. Despite these limitations Amstutz work has still been used as the favoured design theory for use in the mining industry. In reviewing this body of work the author realised that with the advent of readily available computing software it was possible to adopt an iterative approach using Amstutz approximate formulae to find a solution to the original precise formulae, thus eliminating the limitations highlighted by Jacobsen The shear deformation to load characteristics of bolts has long been established (Crawford & Kulak 1968) and used for the plastic design of bolted connections in shear. This relationship is directly transferable to the design of shear studs, typical properties are well known, and actual values easily established in simple lab tests. The author has taken this relationship and modified Amstutz theory (Amstutz, 1970) for shear anchored strengthened liner buckling, to give a more efficient solution, using readily available material properties."

Jan 1, 2019

By T. Donkin, B. Patterson, M. I. Guthrie, J. T. Ross

"Interest in the use of particle-based ore sorting has increased significantly with recent advances in sorting technologies and higher capacities per unit. Particle-based ore sorting has the potential to provide great value in processing lower grade ores from mines while delivering higher grades to the mill, as well as in upgrading waste rock into ore. Typically the focus is on the amenability of the ore to ore sorting and associated reductions in energy, water, and consumables utilization. However, layout significantly affects the installed cost of a processing plant, and the impacts on layout from fitting an ore sorting circuit into the plant plan need to be carefully considered. This paper examines processing plant layout considerations that play an important role in ore sorting projects, including additional crushing and screening requirements, transport of rejected material back to the waste stockpile (mine fleet requirements), and effects on the processing plant footprint. ¦ KEYWORDS Cold climates, Ore sorting, Plant layout RÉSUMÉ L’intérêt porté à l’utilisation du tri granulométrique du minerai a considérablement augmenté au vu des récents progrès réalisés en matière de technologies de triage et des capacités supérieures par unité. Le tri granulométrique du minerai offre une plus-value intéressante en termes de traitement du minerai à plus faible teneur extrait des mines ; il permet par ailleurs l’acheminement vers le concentrateur de minerai à plus haute teneur et la revalorisation des stériles dans le minerai. On met généralement l’accent sur la susceptibilité du minerai au triage et sur les réductions connexes en termes d’utilisation de l’énergie, de l’eau et de biens consommables. Cependant, l’aménagement physique de l’équipement a une incidence non négligeable sur le coût installé d’une usine de concentration, et les répercussions sur l’aménagement de l’installation d’un circuit de triage du minerai dans l’usine doivent être soigneusement examinées. Cet article étudie les considérations relatives à l’aménagement de l’usine de traitement qui jouent un rôle important dans les projets de triage du minerai, et notamment les exigences supplémentaires en matière de concassage et de criblage, le transport de matériau résiduel jusqu’à la pile de stockage des déchets miniers (nombre de camions requis dans le parc minier) et les effets sur l’empreinte de l’usine de traitement. ¦ MOTS CLÉS aménagement de l’usine, climats froids, triage du mineraiINTRODUCTION Ore sorting has been practised throughout history. An early report by Agricola in 1556 documents how metallic and non-metallic minerals were extracted from rocks by laboriously breaking them with hammers and picks and hand-picking selected material with higher grade (Hoover & Hoover, 1950). The concept has not changed, but sorting technology has evolved significantly over the last 20 years"

Jan 1, 2019

By C. Sist, J. Shannon, J. Fossenier, J. F. Adams

With the cleanest and easiest to treat copper concentrates dwindling and becoming harder to find, electrorefineries must deal with the reality of higher impurity anodes. There are well-known strategies for managing nickel, bismuth, antimony, etc. using bleeds (Ni, Bi, Sb, As) or arsenic control (Bi, Sb) or hydrometallurgical add-on circuits (IX, MRT, SX for As, Bi, Sb). However, for integrated copper producers and those producing other base metals it is often worth considering a more holistic, global approach. This paper will discuss both the well-known strategies as well as some global strategies and the role that hydrometallurgy can play in them. Examples will include atmospheric and pressure leaching, selective precipitation and impurity recycling or fixation. INTRODUCTION In the electrorefining of copper, impure copper anodes are electrically corroded, and pure copper is deposited on cathodes by passing DC current through an acidic copper sulphate solution. The anode copper impurities either settle to the cell bottom as insoluble components (anode slimes) or remain in solution with minimal deposition at the cathodes when correct operating parameters are maintained. Consideration of impurities is important in all copper electrorefineries. A typical impure anode contains 98.5–99.5% copper (Schlesinger et al., 2011). Table 1 shows the range of impurities reported for all copper anodes in the 2007 survey of operating refineries (Moats et al., 2007). Also shown is an approximate “limit” of anode compositions within which the majority of refineries operate without additional impurity removal capacity (beyond conventional liberator/bleed circuits). The column is somewhat subjective and meant to be an approximation only since there are many factors that influence impurity deportments and refinery impurity tolerances. More recent world survey data from 2013 show the averages for all impurities trending upward from 2003 to 2013 (Moats et al., 2013). With a competitive market for good concentrate and more copper recycling from electronics (which contain high levels of impurities such as nickel, lead and antimony), this trend is expected to continue through the coming years. The traditional primary method of impurity control is refinery bleed through liberator cells which are employed in the vast majority of refineries (Moats et al., 2013). These are used to control copper (primary liberators), nickel, arsenic, antimony and bismuth (secondary and tertiary liberators). Other methods of impurity control include arsenic addition (upstream in the smelter deporting to anode or directly to electrolyte) to control antimony and bismuth (Kamath et al., 2003), ion exchange or molecular recognition technology (Hur et al., 2005; Navarro et al., 2012) for antimony and bismuth. Many refineries also operate nickel evaporators to remove nickel sulphate before recycling back acid. Some use, or are contemplating using, acid purification units to recycle acid and arsenic without nickel and making nickel carbonate (Kamath et al., 2003; Sheedy et al., 2006).

Jan 1, 2019

By T. G. Joseph, R. K. Soni, M. Curley

"Rapid dampening suspension is a proposed suspension design for ultra-class haulers that is intended to avoid metal-to-metal contact inside a strut and under shock loading, thus improving ride quality and ameliorating fatigue loading issues on a hauler structure. Laboratory testing has shown the ability of the proposed design to reduce the opportunity for bottoming out, that is, metal-to-metal contact between the colliding ends of oleo-pneumatic, two-piece suspension struts during the compression cycle. This paper predicts the performance of a full-size rapid dampening suspension strut by applying scaling rules to test the proposed design based on a set of field data from a Caterpillar 797B ultra-class haul truck operating in the oil sands region of the province of Alberta, Canada. The predicted performance of the suspension strut is compared to that of the original equipment manufacturer model, which was monitored on board the truck during field data collection. ¦ KEYWORDS Haul truck, Original equipment manufacturer (OEM), Rapid dampening, Strut, Suspension RÉSUMÉ La suspension à amortissement rapide est une conception de suspension proposée pour des camions de transport de catégorie ultra-class (des engins dont la charge utile dépasse les 320 tonnes métriques), visant à empêcher un contact métal sur métal à l’intérieur d’une jambe de suspension et dans des conditions de choc au chargement. Elle améliore la qualité du roulement et les problèmes de charge de fatigue sur la structure d’un camion de transport. Les essais en laboratoire ont confirmé que la concep¬tion proposée évitera au cylindre interne de heurter le cylindre externe, autrement dit empêchera le contact métal sur métal des jambes de suspension oléopneumatique en deux parties pendant le cycle de compres¬sion. Cet article prévoit la performance d’une jambe de suspension à amortissement rapide à taille réelle en appliquant les lois d’échelle afin de mettre à l’essai la conception proposée, sur la base d’une série de données de terrain relatives à un camion de transport 797B de catégorie ultra-class de Caterpillar (aujourd’hui remplacé par le nouveau modèle 797F) utilisé dans la région des sables bitumineux de la pro¬vince de l’Alberta, Canada. On compare la performance prévue de la jambe de suspension à celle du modèle du fabricant d’équipement d’origine (FEO), qui a été contrôlée à bord du tombereau pendant la collecte des données de terrain. ¦ MOTS CLÉS amortissement rapide, camion de transport, fabricant d’équipement d’origine (FEO), jambe de suspension, suspensionINTRODUCTION Research basis for the paper This paper is based on the unpublished MSc thesis work of El-Sayed (2003), Santos (2007), and Soni (2009) under the direction of Dr. Tim Joseph within the oil sands–equipment interactions program (OsEIP). OsEIP is part of the Alberta equipment–ground interactions syndicate (AEGIS) surface mining research group, School of Mining and Petroleum Engineering, University of Alberta. The aforementioned work spanned a decade of progressive studies into rapid dampening suspension systems, leading to the scale performance indications highlighted here. Although this paper uses a specific Caterpillar 797B suspension strut for field monitoring and as a basis for scale prediction of a modified rapid dampening suspension strut design, the design scaling principles used here could be applicable to any such design change consideration for an oleo-pneumatic suspension system."

Jan 1, 2019

By G. A. Gamble

"The inlet air velocity profile of any surface mine ventilation fan is an important factor when designing the connecting ductwork from the mine shaft collar to the fan. Deficient fan performance can be the result of ductwork that adds unnecessary pressure loss and/or adversely influences the fan inlet air conditions (velocity profile). The need for optimized inlet air conditions begins with discussing the process of performance testing during the development of the fan performance curve. Additional discussions include design of the shaft collar connection and the connecting ductwork. A preferred design of ductwork for parallel fan installations will be illustrated.INTRODUCTIONThe inlet air velocity profile of any surface installed mine ventilation fan is one of the most important factors to consider when designing the connecting ductwork from the mine shaft collar to the fan. Oftentimes deficient fan performance can be traced to poorly designed ductwork that adds unnecessary pressure loss and/or adversely influences the fan inlet air conditions (velocity profile). Such designs may lead to added power requirement, excessive vibration and noise, and reduced fan performance.Understanding the need for optimized inlet air conditions begins with discussing the process utilized when factory testing takes place during the development of the fan performance curve.Additional discussions include design considerations for the shaft collar connection, the connecting ductwork, and fan inlet. Illustrations of cost savings and pressure losses will be included for audience consideration. The design of ductwork for parallel fan installations on the surface is another issue that requires consideration. A preferred method will be illustrated.The selection of accessory components, such as self-closing doors, can also add to the potential for reduced fan performance. Several components will be discussed.An elementary presentation of the Air Movement and Control Association (AMCA) Standard 201 “Fans and Systems” will be included to provide background for those audience members that want additional technical explanations of the need for a uniform inlet air velocity profile at the fan inlet."

Jan 1, 2019

By V. Prostakova, M. Shevchenko

The copper smelting gas / slag / matte / metal / solids system with the Cu-Fe-Ca-Si-O-S major elements has been a long-term focus of the present overall research program using integrated experimental and modelling approach for the phase equilibria characterisation and development of a thermodynamic database. A systematic investigation of phase equilibria of slag systems in equilibrium with Cu metal is providing information for systems where copper coexists in slag with lead, zinc, and aluminium oxides as major components. Experimental studies involve high-temperature equilibration of synthetic samples; rapid quenching; and measurement of the compositions of equilibrium phases using electron probe X-ray microanalysis (EPMA). Particularly important feature of the present study a wide range of temperatures (660-1670°C) being characterised that reveals major inconsistencies in the existing thermodynamic description of the multicomponent system, and allows to establish the thermodynamic properties from phase equilibria in a reliable way. FactSage-based thermodynamic modelling is integrated with experimental research. Initial thermodynamic assessments are used to identify priorities for experiments, planned to provide specific data for thermodynamic optimisation. Significant improvement in the accuracy of the phase equilibria description is achieved, in particular in the PbO-Cu2O-SiO2, ZnO-Cu2O-SiO2, and Cu2O-CaO- Al2O3 systems in equilibrium with metallic Cu. INTRODUCTION Slags high in lead and copper are generated in primary metal production in the smelting of lead sulfide concentrates and in pyrometallurgical metal recycling systems. The compositions of these slags are varied due to increased fraction of recycled materials in the feed as well as introduction of previously unused chemical elements to modern technology. Therefore, their processing becomes chemically more complex; in that way they contain a large number of different metals. These slags form complex non-ideal solutions (with possible formation of several immiscible slags) that can coexist with stoichiometric solids, solid solutions, mattes and molten metal depending on the bulk composition and process conditions. Predicting the outcomes of smelting and refining processes is becoming increasingly difficult. To assist in the optimisation of these metallurgical processing operations, a comprehensive research program is underway to develop accurate thermodynamic databases for these non-ferrous process systems.

Jan 1, 2019

By H. Henao, F. Canales

The present work evaluated the use of copper ore flotation tails as flux in the process of smelting copper concentrates. For this purpose, experimental and simulated liquidus lines were obtained at different ratios of tail/flux. Experimental variables included temperature, partial pressure of oxygen and sulfur dioxide and the conditions of tridymite or spinel saturation. The results indicate the feasibility of replacing the flux by increasing the temperature of the smelting process by 20°C. Results of simulation using FactSage and HSC confirm that the required increase in temperature can be achieved by increasing the flow of concentrate, enrichment of oxygen or increasing the matte grade. INTRODUCTION In the pyro-metallurgical process of copper production, the smelting stage produces two liquid phases, a sulphide phase rich in copper and another composed mainly of oxides called slag. The slag phase is the product of oxidation of the iron contained in the flotation concentrate. The smelting process which is carried out at temperatures of 1250°C, require the addition of silica as a flux and the injection of air enriched in oxygen (Schlesinger 2011). Currently, one of the most important aspects of the mining industry is the minimization of costs, the optimization of the use of available resources and the reduction of environmental impact. Under this context, the use of flotation tails from as a flux in the copper smelting process has the potential of reduced production costs and generate an environmental benefit by reduce the disposal amount of this waste material Regarding the use of copper tails as flux in the copper smelting process, a thermodynamic simulation study using the FactSage software had been reported in the literature (Parra et al., 2011). The results indicated an increase of 35°C in the temperature the liquidus for the equilibrium matte/spinel and a subsequent requirement of energy in the process of approximately 350 [MJ/ton slag]. Given that the calculated viscosity remains in the same order of magnitude, the melting temperature is a more relevant parameter for the evaluation of the use of tailings as flux.

Jan 1, 2019

By A. E. M. Warner, P. J. Mackey

Copper metal is produced in large or small tonnages in almost all countries of the world—handling raw materials in the form of either as-mined or milled ores, custom concentrates, or other custom materials including scrap and recycled copper. The scale of operations and type of technologies used around the world varies widely. There is a certain concentration of both mining and smelter-refinery production as a total of ten countries produce some 80% of world mined copper, while ten countries—mostly different ones— produce about 80% of smelted and refined copper. As a result, international copper trade is significant. The present paper takes the reader on a virtual tour of the copper plants throughout the world with a focus on smelter facilities. Operations and technology employed at each plant visited are discussed including a brief historical sketch. Future trends identified during the world tour are also discussed. The present authors considered sufficient time was required for a thorough study tour and settled on eighty days—the same as that for the celebrated fictional story of world circumnavigation in the 1870s. INTRODUCTION The celebrated French writer Jules Verne published his book “Around the world in 80 days” in English in1873 and it is the story of Phileas Fogg and his French valet Passepartout circumnavigating the world in 80 days in the fall of 1872 on a £20,000 wager (equivalent to over 2 million pounds today) from the exclusive Reform club in London. This is an interesting period for copper as it started trading on the London metals Exchange in 1876 and the start of global copper production chains started to take off at this time with the rapidly increasing electrification of the world. The production chain includes mining, mineral processing, smelting, refining and fabrication. Since 1880 annual world copper production has increased by over 150 times from 154,000 tonnes in 1880 (nominally considered as smelted copper—essentially the only route at the time to marketable copper) to over 23 million tonnes today (including total refined copper of 19 million tonnes of smelted copper including scrap and 4 million tonnes by solvent extraction-electrowinning), in tandem with increased electricity usage, along with significant transportation usage and for manufactured products (Figure 1).

Jan 1, 2019

By W. Yang, R. Rajasingam, B. Tadesse, K. Mohanarangam

Copper electrowinning is a complex electrochemical process that involves the production of LME grade copper from copper rich electrolyte. The process involves the deposition of the copper ions onto the cathode from copper rich electrolyte with the production of oxygen bubbles at the anode. Acid mist is produced by these oxygen bubbles bursting at the electrolyte free surface. It is an undesired by-product of the Electrowinning process which unchecked could result in mist generation higher than the recommended time-weight-average exposure limit. Various approaches to alleviate the problem have been adopted by companies, all with varying degrees of success. All of these have been attempts to treat the symptom acid mist rather than the inherent problem, often proving expensive and, in some cases, ineffectual. In this paper, a new method was developed for acid mist quantification based on ‘total acid mist’ capture above the EW cell under well controlled conditions. With the use of sophisticated diagnostic analytical tools and measurement techniques it was possible to study all the operating variables including current density, flow rate, temperature, etc. independently and their effect on bubble size, bubble velocity, gas hold-up as well as acid mist generation and its droplet size. Results show that total acid mist capture increases with an increase in current density but remains more or less constant between 300–500 A m-2. Total acid mist also shows an increase with increasing electrolyte temperature. These findings are substantiated with the aid of bubble size and gas hold-up measurements with the transparent EW cell.

Jan 1, 2019

By Alain Tshilombo, Vijay Reddy, Chowdary Meenavilli, Kelvin Buban, Cory Kosinski, Sriraj Meenavilli, Siddhartha Tirumalaraju

The use of artificial intelligence (AI) for process optimization is expected to play an increasingly important role in the future of the mining industry. The objective of AI is to develop a data driven soft (virtual) sensor using historical data that can estimate unmeasurable characteristics of the process and provide appropriate recommendations during operation to optimize the process through continuous learning. The application of AI to a hydrometallurgical process was evaluated by Sherritt Technologies in coordination with NTWIST. Historical operating data obtained from the Ambatovy facility’s High Pressure Acid Leach (HPAL) circuit was used to develop models to predict autoclave discharge parameters based on operating conditions and ore mineralogy. The prediction models were developed in such a way to also allow the user to simulate and test different operating conditions. A second set of models (AI model) were developed based on the prediction models, economic data and operating constraints for a given process unit to identify optimal reagent and steam dosages across the HPAL circuit. The development of these models was significantly complex due to the dynamic and interactive nature of the HPAL process. Despite the complexity of the models, the models were able to predict, with accuracy, the relationship between ore composition, leach autoclaves retention time, acid addition and steam addition with metal extractions as well as levels of impurities in the autoclave discharge slurry. The study showed that AI has the potential to improve the overall operation of a facility through providing tools to assist with training, troubleshooting and process optimization. INTRODUCTION The Ambatovy project, located in Madagascar, is one of the world’s largest nickel and cobalt mining and processing operation, with a design capacity of 60.000 tonnes of nickel and 5,600 tonnes of cobalt per year (Collins et al., 2016). Commissioning and start-up of the Ambatovy mine and plant facilities were completed in 2012, with acid first introduced to the ore leach in March 2012. Commercial production (defined as 70% of design capacity) was achieved in January 2014 and the production level required to achieve financial completion (90% of design capacity for 90 days) was achieved in March 2015 (Valle et al., 2016). Figure 1 shows a simplified flowsheet of the hydrometallurgical pressure acid leach (PAL) process employed by Ambatovy.

Jan 1, 2019