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By J. B. Rubenstein

This work demonstrates the feasibility of using confocal surface profilometry to measure and characterize wear of graphite anode surfaces. This method was tested using anode samples that were electrolyzed for 24 hours in a laboratory-scale magnesium cell with a high oxide molten salt electrolyte. The oxide produced accelerated wear on anodes designed for low oxide electrolytes. Contour maps, which are effective at displaying non-uniform wear, and total graphite consumption values were generated from the collected surface coordinates. Along with both qualitative and quantitative analysis capabilities, this measurement system was shown to have a fine resolution and a low detection limit.

Jan 1, 2004

By J. I. Mathis

"The failure that was utilized for developing this model was a double bench-scale failure, approximately 20 m in height, in the Misery pit at BHP Billiton’s EKATI mine site. The bench that failed was excavated in biotite schist. Due to previous problems with bench-scale toppling failures, this bench was excavated with a 70° inclined, 30 m deep preshear. Upon exposure, the wall was very clean with half-barrels commonly observed from the pre-shear operation.In August 2003, a bench failure of about 1000 t occurred in this pre-sheared biotite schist (Fig. 1). Upon examination it was noted that the foliation that paralleled and dipped at 70° into the face when excavated was approximately horizontal at the top of the failure (Fig. 2). While the failure mode itself appears complex, the failure was apparently driven by three factors:• a low-angle, low-frictional strength fault or discontinuity at the base of the failure area;• water either contributed meteorically from precipitation and/or from permafrost melt; and• foliation planes providing a viable toppling geometry once toe block motion began to occur.The above details are illustrated in Figure 3.After considerable thought and analysis, a model was postulated for the failure.It is thought that the entire failure had been triggered by displacement of a toe block (Fig. 4). This toe block is bounded on the back by foliation, the bottom by a low-angle, lowstrength fault, and the front by the bench face. Water pressures behind the bench face developed forces on the block as can be seen in Figure 5. These forces were sufficient to induce block motion. As can be seen in the relative shear strength diagram in Figure 6, only a small amount of water is necessary in the face to initiate block displacement. Note that in this figure, a simplistic piezometric pressure distribution was assumed."

Jan 1, 2004

By W. M. Silva, Bittencourt. L. R. M.

Three newly developed alumino-silicate refractory bricks for use in safety lining of aluminum electrolysis cells were compared to one commonly used bricks for the same application. It was shown that the increase in silica content and decrease in permeability led to a sensitive decrease in cryolite attack. Both parameters are of utmost importance in selecting bricks for these cells. The reasons for this observation were the formation of a more viscous liquid after the reaction between molten cryolite and the brick, and the reduction of the rate of penetration. Moreover, a novel mortar with high silica content was tested and has shown improved resistance to molten cryolite. The use of oxidizing atmosphere led to increased attack rate in the brick when compared to reducing condition. The opposite effect was observed in the mortars.

Jan 1, 2004

By W. D. Gould, A. Kapoor, K. Morin, P. Bédard

This paper presents the results of a research study that is being conducted by the Mine Effluents Program, Mining and Mineral Science Laboratory (MMSL), Natural Resources Canada aimed at evaluating biotechnology processes for the treatment of nitrogen compounds such as thiocyanide (CNS) and ammonia (NH4-N) which are present in gold mill effluents. A sequencing batch reactor (SBR) technology, commonly used for the biological treatment of municipal and industrial effluents, was used in this study. In the SBR process, the micro-organisms were able to degrade CNS to NH4-N and NH4-N to nitrate (NO3-N) at operating conditions of two 12 h treatment cycles per day, with pH maintained in the 7.4 to 7.6 range, and at room temperature (approximately 21°C) and also at 12 °C. The end products of CNS and NH4-N biological oxidation were NO3-N and sulphate (SO4) that are relatively non-toxic. Partial removal of NO3-N was achieved by biological denitrification reactions in the SBR process. The SBR process effluent was measured to be non-toxic to rainbow trout based on the 96 h acute toxicity test. The microbial consortium isolated from the SBR treating a simulated effluent was able to effectively oxidize CNS and NH4-N to NO3-N in water samples (under batch conditions) collected at three mine sites located in Quebec, the Northwest Territories, and Yukon.

Jan 1, 2004

By V. D. del Valle, T. G. Joseph, J. J. Berezan

Aggressive driving patterns, rough and poorly maintained roads and pit floors, along with the occasional bump and poorly placed load from a shovel can create intense and sometimes serious vibration levels on a heavy hauler. The effects of high vibration have been shown to be of concern for the health of the operator as well as the reliability of the equipment. It is proposed that an onboard vibration warning system based on the ISO 2631-1 standard could be used to help operators reduce the vibration levels experienced in a heavy hauler. The onboard system would consist of a screen that displays the instantaneous vibration in the form of three lights: green (safe zone), yellow (cautious zone), and red (danger zone), as well as an overall vibration exposure or dose for the entire shift. With the utilization of the warning system, it is anticipated that the overall vibration levels will be decreased resulting in improved operator health, a reduction of vibration-induced maintenance, and improved haul roads through reduced impact loading and repair for localized trouble areas.

Jan 1, 2004

By P. A. Geusebroek, N. A. Duke

Abstract - The Lupin mine, located in the central Slave province just east of the western boundary of Nunavut Territory, is a world-class example of a Neoarchean-aged banded iron formation (BIF)-hosted lode-gold deposit. At the minesite the gold-mineralized Lupin BIF, separating stratigraphically underlying psammitic wacke and overlying argillaceous turbidite sequences, delineates the Lupin dome, a hammerhead-shaped F2/F3 interference fold structure occurring at the greenschist to amphibolite facies metamorphic transition within the thermal aureole of the Contwoyto batholith. Detailed paragenetic relationships indicate that peak thermal metamorphism coincided with the switch from regional D2 compression to rapid D3 unroofing of the Neoarchean orogenic infrastructure. Gold initially precipitated with pyrrhotite, replacing amphibolitic BIF at the apex of the Lupin deformation zone, separating the east and west lobes of the Contwoyto batholith. Over the course of associated prograde/retrograde metasomatic overprints, gold was further remobilized during garnet and loellingite/arsenopyrite growth in chlorite-altered selvages of late-forming ladder quartz veins. A metamorphic model of ore genesis, with gold being scavenged and transported by metamorphic fluid that was shed and structurally trapped at the amphibolite recrystallization front, is favored over the previously proposed syngenetic and exogenic models of gold concentration that have tended to polarize genetic interpretations to date.

Jan 1, 2004

By 12670

The Cigar Lake project will develop the world’s second largest high-grade uranium deposit. The Cigar Lake Phase 1 orebody contains approximately 226 million pounds U3O8 at an average grade of 20.7% U3O8. The mine, to be operated by Cameco Corporation, will use a unique water jet boring mining method to cut previously frozen ore. A distinctive ore handling design is required to handle the highgrade ore slurry exiting the mining machines. The ore will be crushed and ground underground, with the ore slurry then pumped to surface. Loaded into purpose-designed containers on tractor-trailer units, the ore slurry will be trucked to Cogema Resources Incorporated’s McClean Lake mill. McClean Lake will leach all of the ore. Forty-three percent of the resulting uranium solution will remain at McClean Lake for processing into yellowcake. The other 57% of the uranium solution will be shipped to Cameco’s Rabbit Lake mill for processing into yellowcake there. Detailed design for the Cigar Lake project is now underway. Barring regulatory or market delays, production could start up as soon as early 2006.

Jan 1, 2004

By G. Plascencia, A. Warczok, M. Zamalloa, T. Utigard, N. Behnood

The objective of this investigation was to investigate interactions between high-grade copper mattes and Rexal 60DB direct bonded basic bricks. The infiltration and attack of Rexal 60DB bricks by copper matte and continuous converter matte was investigated in laboratory tests at temperatures up to 1300 °C. The brick dissolution and infiltration tests did not show any significant difference between the 70% Cu and the 81% Cu mattes. More metallic copper was visible in the pores in the case of 81% Cu matte. An important mechanism for direct-bonded magnesia-chrome brick destruction is that oxysulphides start to infiltrate the brick, followed by slow oxidation of the matte producing metallic copper and cuprous oxide, which then react with MgO and Cr2O3, primarily attacking the direct bonds of the brick.

Jan 1, 2004

By A. Yoshida, H. Miura, S. Yamaguchi, Y. Oyama

A discussion is given on the ionic equilibria and precipitation reactions in seawater based on thermodynamic analysis, in order to understand the solubility of nutrient salts from dephosphorization slag for marine phytoplankton. Solubility of constituent ions in aqueous solution in equilibrium with solid phases are determined using thermodynamic data. It is proposed that CO2 potential defined as log Pco2 should be considered as an additional parameter to the Eh- pH diagram for the ionic equilibrium of slag components in seawater, since magnesium and calcium carbonate precipitation reactions determine the solubility of ligand ions in nutrient salts, such as phosphates, silicate, and sulfate.

Jan 1, 2004

By T. Cutard, H. Marzagui, E. Ouedraogo, M. Roosefid, M. Prompt, C. Deteuf

The present work is achieved in the framework of a French national program on modeling and experimental characterization of the thermo-mechanical properties of refractory materials (PROMETHEREF). This research program is aimed to establish fair models and experimental database and to make it available to industrial partners for numerical simulation of industrial structures made of these materials. The present paper focuses on two silica-alumina refractory castables, an andalusite based one and a bauxite based one. We will present the first rheological characterization results achieved at room on normal and preheated samples of these two refractory castables. Refractory castables are characterized with the help of four points bending tests, compression tests and tensile tests.

Jan 1, 2004

By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

In addition to the harsh environment, materials for high-temperature applications are often subjected to a significant mechanical loading. Several researchers have noted that the rate of oxidation can be affected by stress in a range of materials. We have recently studied this effect in y-TiAl, based on the preliminary work of Magnan and Weatherly which showed that nitridation rates on the tensile side of a flexural creep specimen could be 10 times higher than on the compressive side. We have since developed a four-point bending creep setup capable of controlled atmosphere testing. We present quantitative data on the effect of creep on scale growth under a range of atmospheric conditions. Finite element analysis will also be used to show how modest applied stresses can have a large effect on scale growth rates through the generation of large stresses due to the mismatch of creep rate between the metallic substrate and the scale.

Jan 1, 2004

By Hans de Ruiter

"Delft University of Technology, RWTH Aachen, Helsinki University of Technology and Imperial College established the Federation of European Mineral Programs (FEMP) in 1999 as a legal body to coordinate joint M.Sc. education.By 2003 the number of participating universities in Europe has grown to 9 (in 7 countries) offering 3 different M.Sc. joint programs. Furthermore students from 8 universities in the USA, Canada, Australia and Chile participate through exchange agreements. About 25 companies are associated with FEMP. Further expansion with other clusters of universities is being investigated.So far some 160 students have taken the programs and are working in all parts of the world in a variety of jobs.The European Commission has recently announced the new “Erasmus World” program that will stimulate the offering of joint programs by European universities and offer third-country students and teachers a greater opportunity for mobility and an enhanced European added value. Host European postgraduate courses will be selected for a five-year period. They will receive funding from the Community and a “EU” seal. Around 250 “EU Masters Courses” will be established.The envisaged new Erasmus program and it’s network and operating practices are very similar to those being used by EMC, EMEC and EGEC. Erasmus World therefore offers a great opportunity for further developments with FEMP as the official body.INTRODUCTIONThe current situation in Europe is that globalisation of the supply of mineral resources has caused the larger mining and the manufacturing companies to expand and invest particularly outside Europe. However these industries still have a great significance for the European Union and its members, which means that mineral engineering know-how is still important in the E.U. It was therefore realised in the mid-nineties that is vital to maintain the very high level of knowledge and skill base in mining engineering and mineral technology that currently exists in the E.U., through good and well-balanced education programs."

Jan 1, 2004

By D. Satish Kumar, D. Mazumdar

"95% bulk mixing times in three different size water model ladles of a 140 T cylindrical shaped , dual plug ( located diametrically opposite at mid bath radius position) stirred, industrial ladle were determined experimentally with and without an upper buoyant phase. Based on dimensional analysis and a regression of the experimental data and, it was shown that in the inertial and gravitational force dominated flow regimes, 95% bulk mixing times for a slag-less situation can be described via:[equation]Parallel to this, a large number of experiments were also carried out in one of the water models (D=0.30m) to quantify the influence of an upper buoyant phase on mixing. These indicated that mixing time, operating variables and thermo-physical properties of the upper phase liquid can be correlated via a dimensionless relationship of the type:[equation]in which, Q is the ambient gas flow rate, L is the depth of liquid , (AL) is the slag layer thickness and 6 and t are respectively the surface tension and viscosity of the upper phase fluid The dimensional analysis, regression of experimental data as well as the adequacy of the proposed correlations are discussed in the text."

Jan 1, 2004

Pilot plants for pressure hydrometallurgy represent special design and project execution challenges unique to the industry and to the pilot- and demonstration-scale. Pilot plant projects have different objectives and shorter timescales than commercial plant projects. Design considerations and strategies, and project execution methods that meet the special needs of pilot plant projects, are discussed. Specific guidance is given for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical process equipment, and for the selection of materials of construction for pilot-scale equipment. The balance between the need for process similarity with future commercial operations and the realities of pilot-scale equipment is also discussed.

Jan 1, 2004

By W. Pietsch

For a number of reasons, solids entering and leaving facilities for the treatment of minerals are becoming increasingly finer. Such materials pose problems throughout processing. Solids featuring small particle sizes tend to dusting, result in losses and segregation, exhibit various storage, transportation, and metering problems, and fine particulate effluents can not be easily captured, used and/or recycled. Sustainable mineral processing must minimize the exploitation of natural resources and avoid the need for disposal of wastes. The first requires the use of lower quality raw materials and upgrading, which typically results in the production of fine grained concentrates, and the latter encourages the recycling of wastes and byproducts or efforts to investigate them as sources for secondary raw materials or other beneficial applications. To overcome the difficulties associated with fine particulate solids, size enlargement by agglomeration is necessary. The resulting products have free flow characteristics, do no longer dust or segregate, and are sized and shaped as required for optimum processing. In addition, agglomerated materials may be engineered to feature desirable structure, composition, and a number of related, improved properties. Such engineering may be applied for the modification of fine run-of-mine and up-graded minerals as well as the production of secondary raw materials from by-products or wastes. By the interdisciplinary application of size enlargement by agglomeration waste-free processing of minerals becomes feasible.

Jan 1, 2004

By J. A. McCamley

Gypsum scrap generated from wallboard manufacturing, construction and deconstruction activities in North America, Europe and Japan is a recognized environmental problem. Landfill disposal of this gypsum scrap is problematic, with deposits often creating hydrogen sulphide emissions and metallic sulphide groundwater leachates. Of these regions, Europe is the most advanced in dealing with the issue having enacted legislation, which will come into effect in July 2005 that will strongly encourage gypsum recycling throughout the EU. An estimated 10% to 17% of all gypsum used in the wallboard industry becomes recyclable scrap, which represents approximately 1% of the total waste stream in North America. In the United States, 2.5 to 4.5 Mt of gypsum scrap is generated each year; the volume is similar in Europe (the percentage of total tonnage is less because of the higher use of brick and concrete). The Greater Vancouver region of British Columbia has banned gypsum from its landfills, and as a result, all gypsum scrap is now recycled. New West Gypsum Recycling, a Canadian firm, uses its proprietary technology to process large quantities of gypsum scrap that is reincorporated into new wallboard, at percentages ranging up to 25%. The operation of New West Gypsum Recycling Inc. of Langley, Vancouver is examined as a case study and recommendations are provided as to how other urban regions can implement similar gypsum scrap recycling programs.

Jan 1, 2004

By Ken Dyck, Chuck Edwards

"Cameco's McArthur River is the world's largest high grade uranium mine. Production started in late 1999. Cameco carried out the engineering design and construction management for the McArthur River project, including all aspects of mining, ore handling and ore transportation. The ore composition was expected to vary dramatically (0 to 30% U3O8; 0 to 25% clay; etc). To cope with the composition swings, sizing screens were selected to provide classification in the grinding circuit. The grinding circuit started up close to the design to provide minus 500 micron slurry. The 50% solids (wt) ground ore slurry proved to be difficult to transport to and process at the Key Lake Mill. Slurry containing high concentrations of high density pitchblende (about spgr 8.0) and low concentration of stabilizing clays, would settle in containers. Ore transport efficiency to Key Lake was found to be unacceptable.A test classification cyclone was installed in the grinding circuit at McArthur River early in 2002. The cyclone operating parameters were not typical, but the cyclone was made to work very successfully. Transportation efficiency to Key Lake increased due to more stable slurry. Preferentially ground (fine) pitchblende particles were easier to leach at Key Lake. The radiation exposure for operators and maintenance personnel to handle the more stable slurry was also reduced.The classification sizing screens were removed from the McArthur River grinding circuit and replaced by permanent classification cyclones late in 2002.INTRODUCTIONThe McArthur River mine and Key Lake mill operations are located in northern Saskatchewan, approximately 650 and 720 kilometres from Saskatoon, respectively. Figure 1 is a location map. McArthur River is the world's largest, high-grade uranium mine, with a production capacity of 18.7 million pounds U3O8 annually. (Rosner and Edwards 1998, Dyck 2000, Jamrozek 2000, Rodgers 2001) Proven and probable reserves are more than 473 million pounds U3O8. McArthur River ore, grading on average 21% U3O8, is milled at Cameco's Key Lake operation, 80 kilometres southwest by road. McArthur River production began in December 1999."

Jan 1, 2004

By P. T. O'Kane

The PLATSOL® process, initially developed for the treatment of the NorthMet Cu/Ni/PGM concentrate, has seen over the recent years its applicability extended to include numerous other Cu/Ni concentrates of the same type, as well as other precious metals-containing feedstocks. However, several concentrates were found refractory to the typical PLATSOL® conditions, more particularly so the platinum. Attempts to extend those conditions, such as higher temperatures (250°C), longer retention time, increased oxidation conditions, higher chloride additions, were not successful. Detailed mineralogical investigation of those PLATSOL® leach residues indicated the main refractory mineral to be cooperite (PtS). Further metallurgical investigations showed that a thermal pre-treatment of the concentrate effectively unlocked the refractory platinum minerals for the subsequent leach. Temperatures between 400 and 750°C were tested, with the optimum being found around 650°C. The kinetics of the pre-treatment process were fast, and one hour at temperature proved sufficient. Under those conditions, PLATSOL® extractions were re-established around 95% for both platinum and palladium. From a mineralogical examination of the calcine, it was shown that the effect of the pre-treatment was to transform the cooperite and other refractory sulphides into metallic platinum and alloys, amenable to the PLATSOL®. The implications of the pre¬treatment step for the processing of PGM concentrates arc briefly discussed.

Jan 1, 2004

By M. Bavand-Vandchali, F. Golestani-Fard, S. Khalili, S. Rowshanfekr-Fallah

In the secondary metallurgy of steel, the availability of ladles plays an important role in decreasing the production cost. The refractory lining, therefore, should satisfy optimized quality to grant higher heats. This paper reports the results of an investigation carried out in Iranian Mobarakeh Steel Company in order to increase the lining life of ladles by employing different types of MgO C and Al203 - Mg° - C. The zoning concept was used in replacing the conventional refractories either in slag line or the lower parts of ladle. The number of heats could be improved to almost two times as before. The results are explained in terms of refractory quality as well as zoning approach. The economical impact of this improvement will also be analyzed.

Jan 1, 2004

By Michael Godard, Peter Cleyle

"Suncor Energy’s Project Millennium increased oilsands production capacity by an additional 95,000 barrels per day to its present level of 225,000 barrels per day. This massive venture included an expanded Mine, new Extraction and Upgrading facilities, as well as, steam and utilities infrastructuresIn the Primary Extraction process, removal of the bitumen from the oil sand begins with slurry preparation and is followed by primary , secondary and tertiary separation processes. The final cleaning step of the bitumen froth is the Secondary Extraction process, that removes residual water, mineral and solids to produce a clean diluted bitumen suitable for Upgrader feedstock.This paper will review the flowsheet of the Millennium Primary Extraction facility, from its recent commissioning through the ramp up to design production rates. In addition, new technologies in the Primary Extraction flowsheet will be reviewed.INTRODUCTIONAs conventional supplies of oil and gas are depleted in Canada, the Athabasca oil sands industry of Alberta becomes an increasingly important source of energy. Today, high quality crude from Alberta’s oil sands accounts for roughly 30% of Canada’s daily petroleum production. According to government projections, over the next 7 years, oil sands production is expected to more then double, and by 2010 more than half of Canada’s crude oil is expected to come from the oil sands.Oil sands deposits consist of a layer of sand saturated with bitumen covered by a muskeg overburden and underlain by silt and clay. The oil sand is mined where the overburden is economical to remove, typically less than thirty meters thick. The Athabasca oil sand deposits around Fort McMurrray is ideal for mining. Bitumen can be described as a diverse collection of hydrocarbons, organosulfur, and nitrogen compounds."

Jan 1, 2004