Thermal Reactivation of Carbon Used in the Recovery of Gold from Cyanide Pulps and Solutions

In the majority of recently commissioned gold mines granular activated carbon is used to adsorb gold from alkaline cyanide pulps or solutions. At the same time the carbon also adsorbs many other inorganic and organic species, most of which lower the activity of the carbon. Removal of these foulants is necessary before the carbon is reactivated and recycled. Standard practice for re- storing carbon activity involves high temperature treatment in a kiln - an apparently straightforward unit operation which is not always satisfactorily carried out. This paper presents the results of some fundamental work carried out on the thermal reactivation of carbon in a laboratory rotating pot kiln. The effects of temperature and steam addition on carbon activity were examined and compared with the activity of carbons obtained from a number of commercial kilns. Carbon was also reactivated using a small-scale Rintoul Furnace in which carbon was resistively heated by the direct passage of an alternating electric current. It was established that both elevated temperatures and the addition of steam to hot carbon generally enhanced its activity although peat-based extruded carbons responded a little differently to coconut shell types. Other measurements made included the weight loss and the hardness of carbons as a function of reactivation conditions.