Theory And State-Of-The-Art Of Hydrophobic Particle Aggregation And Flotation

Unlike coarse particles (40-50 µm), the fines (<10 µm) have low collision efficiencies with gas bubbles in flotation process. Among the alternative methods for recovering the fines are their aggregation with coarse particles (carrier flotation) and flocculation of the fines alone (shear-flocculation), prior to flotation. In any case, hydrophobic aggregation is the mechanism involved though the technique is known by different names in literature. This paper deals with theory and state-of-the-art of particle aggregation. To illustrate the dependence of aggregation on particle hydrophobicity, charge and, in turn, the sheer force, the results of quartz-DDACI and galena-xanthate systems are considered. In the flotation of complex ores selectivity is achieved by chemical control and aggregation of particles of the same species is analogous to that; however, more work is necessary on ores for a better understanding of the pulp chemical aspects from the view point of selectivity in aggregation. For a few ores, the results of earlier workers confirm improved recoveries of fines by aggregation prior to flotation.