Theoretical considerations of the cementation of copper with iron

Cementation has been used extensively by chemists and metallurgists as an economical process for the purification and recovery of metals from dilute solutions. The paper deals. firstly. with the thermodynamic aspects of cementation. and. secondly, with the effects of various process variables, such as temperature. stirring speed. initial concentrationof copper ions. pH of the solution, atmosphere, and surface area of the precipitant metal. on the kinetics of the process in the light of the rate expressions.