The Thermal Basis for Explosive Decomposition with Heat due to External heating or reactive ground

Over the past two years a research project has been performed on reactive and hot ground. A key finding is that host materials including carbonates and coal are inhibitors to the reaction of sulphide and nitrates. The mechanism of this inhibition is pH buffering and isolating the surface of sulphide from reactants. It has been identified that acidity is a key driver of the reaction with a pH of 2 required for a reactivity event. A series of decomposition experiments confirmed that reactive and hot ground are essentially the same phenomenon with the heating produced either by the reaction of sulphide with nitrates or an external heat source. The results indicate that the key driver of detonation in reactive ground is energy and heat released from the acid induced reaction of sulphide and nitrate with no indications of sulphide being a catalyst or contributor to detonation apart from being a heat source. There must be sufficient sulphide and thermal insulation to provide and retain enough heat for detonation to occur. A pathway to detonation is postulated whereby the heat travels upwards and results in evaporation of water in the explosive. When the temperature reaches approximately 200°C (400°F) the ammonium nitrate starts to decompose, decreasing the mass of the reacting species. The material in the top layers has reduced density and specific heat hence the temperature of the top region rapidly increases up to >1000°C (1800°F) and may initiate detonation. Field tests on loaded blast holes support this proposed mechanism. Case studies are presented whereby the research findings are used to provide an analysis of historical reactive ground events.