The Removal of Chloride from the Ammonium Sulphate Liquor of the Sherritt Gordon Process

To reduce the corrosion of a stainless steel crystallizer, caused by accumulation of chloride impurity in the liquor during the crystallization of ammonium sulphate, a strongly basic anion exchange resin in the sulphate form may be used to remove the chloride from the liquor. The spent resin may be regenerated with dilute ammonium sulphate.The ions involved are sorbed by the resin in the order Equation 1. The sorption of chloride from the liquor and the regeneration of the resin depend upon the effect of concentration on the formation of the the ion pair NH6SO4. The sulphate ion dominates sorption from dilute solution of ammonium sulphate containing minor amounts of choride; choride ion dominates sorption from concentrated solution.