The non-oxidative dissolution of nickel mattes in aqueous acidic solutions

The techniques used in this study of the non-oxidative dissolution rates of high- and Iow-grade nickel mattes in hydrochloric acid involved leaching and the use of a rotating ring-disc electrode. It was found that the rate of metal dissolution depends on the potential at which the matte dissolves, a maximum rate of dissolution being observed at -0,2 V to 0,3 V (relative to a saturated calomel electrode). The results are comparable with those obtained in work on the dissolution of synthetic nickel and iron sulphides. The adverse effect of excess sulphur on the rate of nonoxidative dissolution is explained in terms of the mixed potential of the reaction. The leaching studies showed the feasibility of processing a high-grade nickel matte by non-oxidative dissolution, and indicate that maximum rates can be obtained in the presence of fairly Iow concentrations of oxidant. A relative selective dissolution of iron can be obtained from the Iow-grade matte under reducing conditions, thus resulting in a significant upgrading of this material. Letter to the Editor Dravo Corporation is seeking information concerning a special method of transporting explosives to aid in designing a large underground oil shale mine in the mountains of Colorado.