The Non-Deal Detonation

Commercial or industrial explosives are mechanically-mixed, fuel-oxidizer composites which exhibit varying degrees of non-ideal behavior. Non-ideality results from a relatively slow and state-insensitive reaction rate (Lee, 1990) and is characterized by C-J pressures, velocities or expansion isentropes significantly lower than those expected from equilibrium, steady-state calculations such as Tiger or BKW (Mader, 1979). This departure results from significant amounts of explosive material which remain unreacted at the sonic point. Energy released by continued combustion within the emergent supersonic region downstream of the sonic point, constrained by local sound speed, cannot flow to the shock front and do work on it. The significant amount of this ‘late energy” and its slow time rate of release must be considered in any blast performance model.