The Metsep Process for the separation and recovery of zinc, iron, and hydrochloric acid from spent pickle liquors

The Metsep Process for the separation and recovery of zinc, iron, and hydrochloric acid from spent pickle liquors by T. H. TUNLEY, B.Sc. (Ch em. Eng.) (Visitor), P. KOHLER (Visitor), and T. D. SAMPSON, Pr. Eng., B.Sc. (Chem. Eng.), B.Econ. (Visitor) A spray roaster has been installed in the Johannesburg area for the treatment of spent liquors from a variety of small pickling operations. A new process was developed for the processing of the liquor that is contaminated with zinc chloride, and a commercial plant was built incorporating this process. An ionexchange plant separates the zinc from the iron chloride, and a liquid-liquid-extraction plant converts the zinc chloride to zinc sulphate and recovers the hydrochloric acid.