The Hydrogen Reduction of Iron Oxides in Calcined Bauxite

The kinetics of the hydrogen reduction of iron oxides in granular calcined bauxite were studied at 550-1,050°C in a shallow bed reactor. The iron oxides behaved as a dispersion of particulate iron oxide in a porous alumina matrix in which the iron oxide particles were reduced independently. The observed rates of reaction were found to be virtually independent of the bauxite grain size. At 800,°C and above, the reduction was multistage, Le.1. Fe203 +2Al203 (matrix) ?2FeAl204, and2. FeAl204? Fe0 +Al203.Reaction 1 was very rapid. Reaction 2 was much slower, the latter stages being controlled, at least in part, by phYSIcal changes of the Fe0 and a-Al203 produced in the reaction. Owing to the observed nature of the material, the reaction rate controlling steps could not be determined.