The Elimination of Nickel from Zinc Plant Solutions Using Dimethylglyoxime

A process for eliminating nickel from electrolytic zinc plant solutions by precipita- tion with dimethylglyoxime (DMG) was developed to enable the Electrolytic Zinc Company of Australasia Limited (EZ) to treat nickel-bearing zinc dust precipitates. These precipitates are leached to recover their Cd and Zn content. The final Zn bearing solutions contain relatively high Ni concentra- tions (20-100 mg/1) and are treated with DMG and then neutralized to pH 4.6-4.8. The pre- cipitate is filtered off and the solution returned to circuit. DMG consumption is about 200% of theo- retical requirement, and Ni removal is 80% complete overall.