The Dynamic Modelling of Caustic Concentration in the Bayer Process

In the Bayer process, bauxite is leached with caustic soda, forming a solution of sodium aluminate, from which hydrated alumina is precipitated. The efficient operation of the continuous form of this process requires that the concentration of caustic soda be controlled. A computer simulation of the concentration of caustic soda has been conducted to provide information, regarding the dynamic behaviour of caustic concentration, which is not available from normal plant data. The basis of the simulation is a state- space model of an alumina refinery, linearized about the normal operating condition. The formulation of the model, with the relevant approximations and assumptions, is outlined. The simulation of the mudwash section of the. plant is described in detail. A continuous model of the mudwash, having time-varying coefficients, was driven using operating data from an alumina refinery. The modelled response showed reasonable agreement with the recorded plant response.