The Dissolution Behavior Of Metals From Silver/Copper Alloys In Ammoniacal Solutions

The dissolution behavior of silver and copper from silver/copper alloys in ammoniacal solutions was investigated using a rotating disc. Oxygen was used as an oxidant. The effects of the alloy composition, concentration of lixiviants, stirring speed and temperature on the overall dissolution kinetics were studied. Three silver/copper alloys (containing 76.7, 46.9 and 24.1% silver) were used in this study. The rates of dissolution for these alloys were compared to that of pure silver and copper under the same testing conditions. Emphasis was given to the galvanic effect on the overall dissolution rates.