The Dissolution Behavior Of Metals From AU/AG/CU-Alloys

The dissolution behavior of metals from Au/Ag/Cu-alloys has been studied using rotating disc electrodes in solutions containing acids, cyanide, and ammonia. Electrochemical methods as well as leaching tests were adopted in this study. The results showed that there was no galvanic effect on the dissolution of metals from homogeneous alloys. In aerated cyanide solutions, the dissolution of gold, silver, and copper from their alloys was partly controlled by surface chemical reaction, but largely by mass transfer. On the other hand, the galvanic coupling effect played a very important role in heterogeneous alloy systems.