The Development and Application of the Selective Zinc Precipitation Process for Controlling Impurities in Electrolytic Zinc Plant Circuits

The Selective Precipitation (Basics) Process is a means of controlling impurities such as the ions of Mn, Mg, and Cl as well as sulphate and water, in an electrolytic zinc plant circuit. This is achieved by precipita- ting zinc selectively as a basic zinc sulphate from a portion of impure circuit solution. The impurities remain in the solution, which can be discarded, while the zinc, substantially free of impurities, is returned to the main circuit by using the precipitate as a neutral- ising reagent. A description of the process and its development to a full scale operating plant at the Risdon Works of the Electrolytic Zinc Company of Australasia Limited is Presented.