The Corrosion of Metals

Around no subject of technical )uterest have prejudice and wrong-thinking in the past so wrapped a web of obscurity as that of the corrosion of metals.It is a matter which has primarily concerned the engineer, but the paucity of his training in chemistry and electrochemistry has been the stumbling block to a better understanding of its mechanism.Now that the more important conditions controlling corrosion have been scientifically.established, it can be seen that, with the exception of but a few of the minor points, the electrochemical laws enunciated by Faraday, Helmholtz; Nernst, and others, are sufficient to include all the facts of the process.The word corrosion (derived from the Latin rodere-to gnaw) is so often wrongly applied that a definition at this stage would be useful. As now understood, it means the dispersion and waste of the useful solid metal by conversion into a useless compound which mayor may not be retained on or near the metal remaining.Commonly the presence of these compounds is regarded as evidence of corrosion, but the converse is not necessarily true; the lack of visible corrosion products on a clean surface of metal is no criterion of the absence of this change. It may be difficult to prove that the erosion of such a surface has been caused by chemical and not by mechanical effects alone.