The Anodic Behavior of Electro-deoxidation of Titanium Dioxide in Calcium Chloride Melt

Since Fray-Farthing-Chen (FFC) Cambridge process was proposed in 2000 for electrochemical extraction of titanium from titanium oxide, a great quantity of research has been carried out to investigate the mechanism of the electro-reduction of the process. Results show that the intermediate products of perovskite phases are inevitable during the electro-deoxidation process. In this paper, a new perspective focus on the anodic behavior was applied. The behavior of the graphite anode with different times has been investigated. Although the main anodic process in the electrolysis is the oxygen evolution by means of the CO2. The interphases of calcium species appeared on the cathode are closely related with chlorine ions in the molten CaCl2. In addition, the released CO2 from the anode is related with the formation of CaCO3 which floated on the surface of the molten salt.