Sintering activity of nano-powders used in the binding systems for refractory castables

Sintering and ceramic bonding in refractory castables take place mainly in the binding system during the first heat-up and in service. Consequently the strength and the corrosion resistance of the hot face layer depend on the sintering ability of the complex mix of ceramic powders constituting the binding system. As a result, the use of nano- sized reactive powders in the binding system mixes would activate the sintering and enhance the ceramic matrix formation at temperatures below 1300°C. Our work presents the experimental data on sintering behavior of binding systems containing magnesium aluminate and alumina nano-powders in the temperature range of 800-1450°C. The results indicated that a ceramic matrix, similar to high temperature fired bricks, could be generated after firing at the relatively low temperatures available in the non-ferrous smelting furnaces.