RI 8656 Electrochemical Studies of Platinum-Group Metals in Molten Alkali Metal Cyanides

The Bureau of Mines has studied the electrochemical parameters important to the preparation of coatings of the platinum-group metals. Using molten mixtures of sodium and potassium cyanides in an inert atmosphere, techniques have been developed that permit the preparation of baths for platinum, rhodium, and iridium electrodeposition. Cyclic voltammetric and slow sweep rate linear polarization techniques have been utilized to determine optimum potential and current values for preparation of plating baths and for the electrodeposition of coatings. Techniques are described for the deposition of platinum and rhodium coatings at near 100 percent anode and cathode current efficiencies, and for iridium at approximately 80-percent efficiency. Palladium deposition from these molten cyanide baths remains un-satisfactory. The chemistry of the palladium-containing cyanide bath is discussed. Examples of scanning electron microscope photomicrographs of typical platinum coatings are presented. Techniques are described for the preparation of platinum coatings on large objects.