RI 7337 Mine Water Research - Catalytic Oxidation Of Ferrous Iron In Acid Mine Water By Activated Carbon

Laboratory batch-flow tests conducted on a highly ferruginous acid mine water with an activated carbon showed that ferrous iron is rapidly oxidized. This indicates that air oxidation of ferruginous acid in mine waters is catalyzed by activated carbon. The ferrous iron content of an acid mine water flowing through an aspirated activated carbon column was reduced from about 700 to about 10 parts per million in less than 1 minute. Highly efficient ferrous iron oxidation was achieved by conditioning the activated carbon by repeated treatment with acid mine water and air. The reaction proceeds rapidly in the acid environment (pH about 2.5) engendered by ferrous iron oxidation. The activated carbon was used repeatedly with little loss in efficiency, no discoloration, or solids deposition. In these batch tests, about one-third of the iron was adsorbed by the carbon, but with continuous flow, little iron adsorption is expected. Incorporating a catalytic oxidation step in the treatment of acid mine waters containing ferrous iron would greatly facilitate neutralization--precise control of pH, lower reagent costs, elimination of aeration equipment, and smaller holding ponds.