Removal of Cupric Ions from Industrial Effluents by Adsorbed Organofunctional Silanes

Metal ions associated with effluent streams pose an increasing environmental problem for the mineral industry. Various techniques currently in use to combat this problem including bioremediation, chemical precipitation, and ion exchange are reviewed, and their relative advantages and disadvantages discussed. An alternative technique for metal ion removal, adsorption on surface modified alumina substrates is presented. Alumina surfaces were modified by adsorption of organofunctional silanes, and metal ion removal occurs by chelation of the ion by the adsorbed silane molecules. Experimental data is presented for the removal of cupric ions by this method and is compared to cupric ion removal by adsorption on alumina without prior surface modification.