Recovery of Metals from Metal Mixtures by Alkaline Leaching

A leaching treatment was investigated to recover metals including rare earths from the mixtures of hydrogen storage alloys and nickel hydroxide. A potential-pH diagram of the La-Ni-H20 system including the domain of stability of LaNi5 was drawn to find appropriate leaching conditions. Alkaline solutions containing ligands that form complexes with nickel ions were supposed to be available to separate hydrogen storage alloys from the mixture. When the mixture was leached with ammoniacal alkaline aqueous solutions, the nickel hydroxide was dissolved and the hydrogen storage alloy was recovered as its original alloy.