Pulp Chemistry, Surface Chemistry, and Flotation

The bulk and surface chemistry of metal ion hydrolysis and precipitation and the redox chemistry of metal ions, sulphur, and other species is central to an under- standing of flotation. The paper contains a review of general hydrolysis-redox chemistry appropriate to the flotation process, and a model of natural and collector-induced flotation of sulphides is constructed. The practical application of the model to real flotation systems is then explored with a view to better under- standing of the chemistry of selectivity and grade control.