Pressure Oxidation Of Silver-Bearing Sulfide Flotation Concentrates

Silver-bearing, bulk sulfide concentrates from several Peruvian mines were autoclaved in a l9-L (5gal) laboratory autoclave in Lima, Peru. Cyanidation of autoclaved concentrates, following a hot lime jarosite destruction step, extracted more than 98% of the silver and more than 95% of the gold. Autoclave operating parameters, such as time, temperature, pulp density and autoclaved solids recycle, were investigated and reaction rates determined. The problems of excessive heat generation, silver solubility during autoclaving and formation of pellets containing unreacted sulfides were addressed. The data presented will be used to design a continuous autoclave pilot plant to provide reliable scale-up data for a 50 to 100 t/d (55 to 110 stpd) facility.