Pressure Leaching Of Indian Coals At Elevated Temperature For Producing Low Ash Clean Coal

With implementation of stringent environmental regulations, ultra clean coal technology development programs have gained significant importance worldwide. As far as Indian scenario is concerned, most of the coals present in India are of drift origin and low grade, containing high mineral matter varying from 15% to greater than 50%. The inorganic or ash constituents of Indian coals are finely disseminated through the organic or carbonaceous constituents so, that commonly used physical beneficiation techniques are of only limited value in affecting separation. Chemical processes involve addition of chemicals, which react with the mineral matter and allow its easy removal. The present study envisages the effect of aqueous alkali leaching followed by acid washing on the removal of mineral matter from two different captive coals of Tata Steel at elevated temperature and pressure. The experiments are conducted at desired conditions using a bench scale pressure reactor set up having proper data acquisition and control system. The research study revealed, that it is possible to reduce the ash content up to 70% by this method. The alkali content of the product clean coal does not increase whereas the silica and alumina content reduces by nearly 58% and 62% respectively. Significant reduction in the phosphorus content is observed after the acid treatment. The crucible swelling number of the feed coal improves after the treatment. The mechanism of demineralisation was evaluated by analyzing the coal samples before and after the alkali and acid treatment using scanning electron microscope (SEM). Because of the acidic nature of the silicates and aluminates, they dissolve into the NaOH solution and form sodalite. Sodalite is partially soluble in the alkali solution. The hydrates formed during alkali treatment are partially removed due to acid wash. This study in overall provides an insight into possible alternative methods of beneficiation for removal of ash from high ash Indian coals.