Preliminary Design And Analysis Of Recovery Of Lithium From Brine With The Use Of A Selective Extractant

Lithium requirements in the next few decades for batteries and controlled thermonuclear fusion reactors (CTR) may exceed the availability of the current mineral and brine reserves. It is thus prudent to search for new reserves and resources to satisfy these and future lithium applications. The lithium content of the waters from the Smackover oil field. located in the Gulf Coast region of the United States, ranges from 100 to 500 mp/l and could represent a substantial new reserve. Experimental evidence described in the literature indicates that a specific chelating agent dipivaloylmethane (DPM), of the diketone type, has a specific selectivity toward lithium in the presence of other metal ions in aqueous solutions. Based in part on this unique property of dipivaloylmethane, a conceptual design of a full-size plant to extract lithium from the Smackover brine is presented in this paper. This study includes alternate flow-sheet development, design information on the major units of the process, energy requirements, and an economic analysis of a facility capable of producing 106 kg of lithium per year. The economics of three different process concepts depend primarily on the amount of water needing to be evaporated from the initial oil-field feed waters in concentrating the brine. The results, as a function of production rates, are indicated only in a general manner.