PGM Recovery from a Pregnant Leach Solution Using Solvent Extraction and Cloud Point Extraction: A Preliminary Comparison

"Global demand for the three platinum group metals (PGMs) Pt, Pd, and Rh has been steadily growing due to their widespread use in emission control, industrial catalysis, and numerous other applications. The primary supply of PGMs is currently the mining industry. However, legislative, operational, and environmental challenges faced by many mining operations result in erratic supply patterns and deficits for these three metals. Naturally, recycling scrap material to recover Pt, Pd, and Rh has therefore aroused research interest in the scientific and engineering communities. Given that the majority of the global demand for these three metals is driven by emission control devices, autocatalytic converters are therefore a significant source of already processed and beneficiated PGMs for recycling.Although pyrometallurgical processes dominate the recycling industry, hydrometallurgical processes may offer certain advantages, chief among these being lower emissions and reduced energy consumption. In this investigation, scrap converter material was leached in acidic chloride media and the leach liquor subjected to solvent extraction and cloud point extraction (CPE) to recover the PGMs. The recoveries for Pt and Pd using Alamine 308® dissolved in kerosene with decanol as a modifier were 95% and 81%, respectively. The maximum recoveries using CPE after complexation with 2-mercaptobenzothiazole (2-MBT) in the presence of Triton X-100 and tin (II) chloride dihydrate as a reductant were 97% for Pd, 96% for Pt, and 91% for Rh. This demonstrates that CPE, although relatively new, may have some potential as a breakthrough PGM recovery technology. IntroductionPlatinum group metals (PGMs) have found a wide variety of applications in different industries due to their chemical, catalytic, and physical properties. PGMs are essential in automobile emission abatement, petroleum refining, and the pharmaceutical and electrical industries (Carabias-Martinez et al., 2000). However, the abundance of PGMs in the Earth’s crust is low and their primary sources are fast depleting (Crundwell et al., 2011).The high demand for PGMs, together with social, economic, environmental, and political aspects related to their production, has led to concerns about their future supply. This has resulted in renewed interest in recycling end-of-life material. PGM supply from recycling has doubled over the last decade, and currently contributes 22% to global supply (Johnson Matthey, 2016). This is in part due to the environmental, social, and operational challenges associated with mining of PGMs. For example, labour unrest, energy cuts, declining commodity prices, and declining ore grades have collectively made the mining landscape economically challenging (KPMG, 2015). On the other hand, the high content of PGMs in secondary sources makes their recovery from the increasing quantities of waste products important from a resource conservation viewpoint. Moreover, PGMs obtained through recycling have been demonstrated to have a 1% environmental cost from a life-cycle perspective, whereas PGMs obtained from mining contribute the remaining 99% of environmental cost (Bossi and Gediga, 2017). Sustainable resource recovery and the economic incentive of recycling have therefore been major drivers to justify investment in PGM recycling. The autocatalytic converter industry accounts for about 70% of the global consumption of these metals (Johnson Matthey, 2016) and therefore recycling spent converters has become a major source of Pt, Pd, and Rh (Figure 1)."