Paracoethite for Iron Control at the Zinifex Hobart Smelter

In 1997, the Zinifex Hobart Smelter ceased ocean disposal of jarosite and the flowsheet was converted to reject iron as paragoethite. This paper describes the evolution of the flowsheet since the changeover and considers future flowsheet developments. The major change to the flowsheet has been an increase in the silica content of the calcine resulting from treating increasing levels of Century concentrate. The high silica levels impacted on the paragoethite precipitation stage, causing a deterioration in the settling and filtration characteristics of the paragoethite and an increase in the contained zinc level. The implementation of a two stage neutral leach step has enabled the flowsheet to cope with the higher input silica levels. Future developments include an understanding of the form of the zinc in the paragoethite and options to lower the zinc level to improve the overall zinc recovery.