Nickel production from low-iron laterite ores: Process descriptions

"Process descriptions are provided for the following ten plants that treat high-magnesia lateritic nickel ores (saprolite) by pyrometallurgical means: PT Aneka Tambang; Cerro Matoso S.A.; Falconbridge Dominicana C. por A.; Hyuga Smelting Company Ltd.; Larco (Societé Minière & Métallurgique de Larymna); Loma de Niquel; Le Nickel, SLN-Eramet; Nippon Yakin Kogyo Company Ltd.; Pacific Metals Company Ltd.; and PT Inco Indonesia.Flowsheets, equipment information,chemistry and production data have been compiledfor plants based on both information providedby the companies and on calculated massand energy balances.IntroductionNickel is of vital importance to modern society. Without it, we would not be able to enjoy many of the things that we take for granted, such as computers, airplanes and stainless steel appliances in our homes and workplaces, to mention a few.Nickel occurs in nature both as sulphide and oxide ores. Approximately 36% of the nickel reserves in the Western World occur as sulphide and 64% as oxide ores. Sulphide ores respond to concentration processes, whereas, oxide ores do not. Sulphide ores mined at 1% nickel can be readily concentrated to 10% nickel, whereas, oxide ores cannot be concentrated and therefore have to be processed as mined.Laterite ores are normally classified intotwo groups:1. The high-magnesia ores, saprolites or serpentines, are, as a rule, processed by smelting. The main reason for this is that the nickel replaces magnesium in the magnesium-silicate lattice. To be able to recover nickel, the lattice has to be destroyed. This can be achieved by smelting under reducing conditions.Acid leaching is also possible, but in this case, large amounts of MgSO4 or MgCl2 will be produced making it costly to regenerate the acid.2. The high-iron, low-magnesia ores are known as limonite. The nickel is relatively loosely bonded to goethite and hence can be recovered by selective reduction followed by ammonium-ammonium carbonate leaching. In recently developed processes, these ores are also being extracted by acid pressure leaching, with high Ni and Co recoveries.This paper focusses on the production of ferronickel and nickel matte from the highmagnesia ores."