Modifying Pressure Oxidation To Enhance Silver Leach Recoveries

It has been demonstrated for two totally different silver bearing and cyanide refactory concentrates that the formation of silver jarosite can be prevented through the addition of iodide to the autoclave feed. A molar ratio of r/ Ag+ of no more than 1 was sufficient to raise silver extractions in a subsequent cyanide leach from 4% after autoclaving without iodide addition to 98% for the sulpho-salt concentrate and from 15% to 97% for the pyritic acanthite concentrate. Flowsheet proposals will be discussed to prevent loss of the iodide additive. The use of chloride instead of iodide will also be reviewed.