Manufacturing and Aging Effects on Pentolite Boosters

Pentolite is a class of high explosives containing trinitrotoluene (TNT) and pentaerythritol tetranitrate (PETN) with PETN content typically ranging from 40 to 60 wt%. Manufacture involves melting TNT, 80 °C, followed by addition of PETN and trace ingredients to form a homogeneous mixture. Once a mix is ready to be poured, several factors can influence the behavior of the finished product including how long the mix has been at temperature and cooling rate. After the manufacturing process has been completed, storage conditions combined with manufacturing conditions may cause physical changes. Two such changes explored were exudation, liquid exuding from solid boosters, and ratchet growth, irreversible volumetric expansion. Exudation is principally caused by excess water in the process. Ratchet growth is a common phenomenon of nitroaromatic compounds such as TNT where time and temperature fluctuations can cause materials to increase volume, simultaneously decreasing density. Although neither phenomenon affects common attributes such as sensitivity, performance, and shelf-life, both can cause issues in storage and handling. In this study pentolite was cast into various forms under different manufacturing conditions and evaluated over several months of controlled storage conditions including ambient, temperature cycling and elevated isothermal. Subjective and objective measurements were made throughout the evaluation period with the aim to determine the preferred storage methodology.