Isotopic Values of Native Sulfur, Barite, Celestite, and Calcite: Their Relationship to Sulfur Deposits and to the Evolution of the Delaware Basin (Preliminary Results)

Native sulfur occurs with barite, celestite, and bioepigenetic calcite in the Culberson, Pokorny , and Leonard Minerals deposits, Delaware basin. The sulfur in these deposits, in "castile" masses, and in deposits of the Fort S tockton district have 6 34s values between +9 and -15. Native sulfur in the caves of the Guadalupe Mountains is somewhat lighter [(634s = -15 to -25)]. Barite in the Culberson, Leonard Minerals, and Comanche Creek sulfur deposits have 63% values of +35 to +73; celestite in the Culberson and Leonard Minerals occurrences have values of +38 and +36, respectively, and 87Sr/86Sr values of 0.707808 and 0.708138, respectively. Barite associated with sulfide, deposits, Guadalupe Mountains, have [634s] values of +41 to +62. Barite at Seven aeart Gap, Apache Mountains, is somewhat less enriched in heavy sulfur [(634s = +14 to +37)].