Investigation of Si Containing Additives on Properties of Andalusite ? Graphite Bodies Used in Pig Iron Ladles

The main application of refractories based on andalusite in ferrous metallurgy are in air heaters of blast furnaces, mobile mixers, and hot-metal transfer, pig iron ladle, steel-casting, and intermediate ladles. Three specific properties of andalusite are very interesting for the production of high-quality shaped and unshaped mullite refractories: being free of water, its crystal a remains stable without changing its density or volume after firing and therefore has no internal porosity .Graphite additives due to its great wetting ability play an important role in raising the property of refractory bodies. In order to improve properties of andalusite graphite bodies, oxidant agent for increasing in hot strength and oxidation resistance can not be avoided. In this research, firstly 8 pig iron ladles from ESC(esfahan Steel company) with different conditions selected and monitored during usage to determine of main factors affecting on corrosion of refractories. Results showed that tap to tap time, undischarged pig iron ,penetrated pig iron are the main ones.Literature studies showed that the graphite addition help to thermal shock resistance and liquid penetration(steel,pig iron) effect. In this research particle size distribution of aggregates containing andalusite and graphite determined by andreazen equation. Then different mixes with different percentage of graphite,Si, FeSi, SiC prepared by uniaxially pressing under 1500kgf/cm2 pressure by adding 4%wt novalak resin and 0.4%wt HMTA as hardner. Samples fired at 1100-1500oC under reduction atmosphere. According to specific standards density, porosity and CCS measured. Analytical tests such as XRD, SEM were carried out on sample selected from point of view of mechanical properties at different temperatures. Results showed that optimized amount of Si and Fe-Si for _-SiC formation in body is 4 and 6 %wt respectively at 1500OC. XRD and SEM analysis on sample with Fe-Si additives showed no destructive phase through the matrix, also SiC additives not only increase oxidation resistance but also no effect on thermo-mechanical properties.