Institute of Metals Division - Precipitation of Mo2C on a Free Surface (TN)

In the course of annealing studies on molybdenum, it has been observed that a carbide precipitates preferentially on internal and external surfaces. The evidence for this is as follows. Electropolished bend specimens prepared from two grades of commercial molybdenum were loaded in a closed but unsealed tantalum can, and were annealed for 1 hr at 2000°C under a vacuum of 1 x 10-4 torr. The compositions of these materials are summarized in Table I. The samples were then slowly cooled at an average rate of 10°C per min, and were examined when cool. The surfaces of specimens prepared from Molybdenum A were consis- tently clean and featureless, except for thermally etched grain boundaries, see Fig, l(a). On the other hand, Molybdenum B had surfaces containing many needle- and featherlike markings, see Fig. l(b). These features were present in all surface grains, and within a given grain belonged to families