Improved PGM-Chromite Selectivity in a Pneumo-Mechanical Flotation Cell

"The Upper Group 2 (UG2) reef in the Bushveld Complex in South Africa hosts an estimated 40% of the world’s Platinum Group Metal (PGM) resources. The processing of this ore via flotation poses two particular challenges: limiting the levels of chromite in the concentrate to reduce downstream smelting problems, and enhancing the recovery of ultrafine (typically -10 micron), liberated PGMs. Conventional ways of suppressing the entrained chromite, such as froth washing, is not effective in PGM operations, which are dominated by mechanical cells. The recovery of fine particles is hampered by low collision efficiencies with air bubbles, as well as oxidised surface layers especially in tailings operations. This paper documents the results of laboratory tests on a run-of-mine PGM UG2 ore, investigating the application of a pneumo-mechanical column (PMC) and its effect on PGM flotation and its selectivity with regard to chromite. A key feature of the device is the stage-wise release of aerated slurry from an agitated downcomer, thus creating conditions where the superficial velocity profiles of air and slurry change axially within the separation zone. This aids segregation of the silicates and chromite-rich fractions in the separation zone, concentrating the latter towards the bottom of the column and minimising its entrainment into the concentrate. Comparison of the performance of the PMC to that of mechanical laboratory cells under equivalent operating conditions showed improved PGM flotation kinetics and recovery. This was accompanied by a decrease in gangue recovery compared to the mechanical cells by more than 40%, thus doubling the final rougher concentrate grade from 50 to 100 g/t. Significantly, whilst the overall Cr2O3 recovery was reduced by more than 60%, the selectivity (PGM recovery vs Cr2O3 grade in the concentrate) was doubled.INTRODUCTIONThe Bushveld complex in the northern part of South Africa hosts the world’s largest reserves of Platinum Group Metals (PGMs), representing approximately 40% of the total PGE. It is characterised by three main PGM bearing reefs, namely Merensky, Upper Group 2 (UG2) and the Platreef. The Merensky and Platreef are dominated by silicates in the form of pyroxenites, and carry economically recoverable amounts of copper and nickel, in the form of chalcopyrite and pentlandite. The UG2 on the other hand is a chromitite ore with chromite as (ideally, FeO.Cr2O3) the most abundant gangue, often constituting more than 70% by mass with a PGM grade of around 4.5 g/t. Other key gangue minerals are pyroxene, feldspar and talc. The PGEs occur in a wide variety of minerals, with platinum and palladium sulphides typically accounting for about half of the total. Base metal sulphides such as chalcopyrite, pentlandite and pyrrhotite occur in only very minor amounts, accounting mostly for less than 0.1% by mass."