Gold Extraction From Low Grade Carbonaceous Ore Using Thiosulfate

The U. S. Bureau of Mines has been investigating the application of thiosulfate to recover gold directly from low grade refractory carbonaceous ores for the past four years. Statistical experimental methods were used to determine the effects of various leaching parameters on both gold extraction and thiosulfate consumption. Seven variables were investigated, including thiosulfate, copper, ammonia, sulfite, and sulfate concentrations, leaching time, and leaching atmosphere. This information was used in face-centered cubic (FCC) surface response experiments to define the optimum leaching conditions for a low grade ore. Two models were generated from the data to predict gold extraction and thiosulfate consumption as a function of the leaching parameters. The models predicted a gold extraction of 67 pct and reagent consumption of 2 kg [S2032/mt ore at 0.25 M S2032-, 0.0014 M Cu2+, 0.27 M NH,OH, 0.00625 M SO;-,] and leaching for 16 h. Actual tests resulted in 62 pct gold extraction with 0.93 kg S2032- consumed/mt ore. Subsequent column leaching tests have further demonstrated the viability of applying this technology to recover gold from carbonaceous ores without first pretreating the material. Gold extractions in the column tests ranged from 69 to 78 pct with thiosulfate consumption ranging from 0.4 to 5.4 kg/mt ore. These results compare to <5 pct gold extraction using standard cyanide leaching conditions.