Fundamental Aspects Of Gold Cyanide Adsorption On Activated Carbon

The carbon-in-pulp process for gold processing depends on the adsorption of dissolved Au(CN)2- from solution onto activated carbon. Our work shows that coconut and peat based carbons have the same mechanism and kinetics of adsorption. There is no contribution to the bonding from carbon-oxygen functionalities on the carbon surface, as has been invariably supposed in all previous theories for the mechanism of the reaction. It is shown that Au(CN)2- is reversibly adsorbed intact on, and parallel to, the graphitic planes of the carbon. The physiochemical basis of the measurement of carbon reactivity for gold adsorption is discussed.