Flotation of a High-Grade Free-Milling Gold Ore Using Xanthate and Carboxylic Acids as Collectors

"Laboratory-scale tests were carried out to investigate the response of a high-grade (~143 g/tonne) well-liberated gold ore to flotation using two collector types. Octyl and amyl xanthates, representing conventional types of collectors, were tested against an n-octanoic and hexanoic acids under moderate and high redox potential conditions. The latter was based upon a suggestion in literature that monocarboxylic acids are able to adsorb onto the surface of gold at redox potentials near 600 mV (SCE). This investigation did not demonstrate that these carboxylic acids could function as collectors for gold in real ores. In fact, they appear to have slightly depressed gold. However, the results demonstrated that octyl and amyl xanthates acted as highly effective gold collectors for this ore and that an increase in the collector dosage led to an increase in recovery for all mean particle sizes. In some tests, gold recoveries of around 95% were attainable in concentrates with grades around 6 kg/tonne, indicating that xanthate flotation remains a viable means of concentrating gold even at coarse grain sizes. Various aspects of the process such as grade-recovery performance and recovery by size are discussed.INTRODUCTION Three methods are used for the recovery of gold in mineral processing, either alone or in combination: gravity concentration, cyanidation and flotation. Gold occurs as a by-product in some ores together with platinum group metals and as the primary metal in other ores in the form of native gold and electrum, which are alloys of gold, silver and minor amounts of copper. Flotation is a viable method for recovering liberated gold where the gold is visible under an optical microscope (greater than 1 µm in size) and where the attachment of gold grains is not prevented due to bubble loading by competing minerals. It is generally known that grains finer than 150 µm in size will float with most collectors."