Expan - Ammonium Nitrate Prill for Blasting, Technical Aspects and Applications

Unlike molecular high explosives, commercial explosives based on ammonium nitrate do not detonate ideally according to the theoretical model for steady state, one-dimensional detonation. One of the reasons for this deviation from ideal detonation is the slower chemical reaction, due to less intimate contact between the oxidiser and fuel components. It is well known that the inclusion of gas pockets, such as microballoons, in the formulation of ammonium nitrate based emulsions and watergels enhances the performance of these explosives. Various different interpretations of the “hot spot” theory have been proposed to explain this phenomenon.