Environmental Fate of Flotation Reagents Used in the Florida Phosphate Industry

Perceived environmental impacts from flotation reagents used in the phosphate industry have been of concern for nearly a decade. A research program was initiated to determine the distribution, fate, and consequences of flotation reagents (fatty acids, fuel oils, and amines) within the environment. Therefore, laboratory investigations of biodegradation and soil attenuation of the reagents were conducted along with field flotation mass balances and groundwater investigations in clay settling, sand tailings, and undisturbed areas. Sample analysis and a reagent mass-balance model indicated that most reagents are distributed in clay settling and sand tailings areas. Groundwater analyses showed no fatty acids or amines in any of 19 surficial or intermediate aquifer water samples. In contrast, fuel oils were detected in the surficial aquifer at all sand tailings areas in concentrations ranging between 8.5 and 0.5 mg/L. Fuel oil was also detected in trace amounts (0.6 mg/L) in one intermediate aquifer well located in an active sand tailings area. All fuel oil concentrations detected were very low and, coupled with a biodegradation rate of approximately 10% per month, all concentrations should be within reference levels in six months. Based upon the results of this study, use of flotation reagents in the beneficiation process of the Florida phosphate industry present no long-term threat to the environment.