Emulsion Breakers for Waste Explosives

Ammonium Nitrate Emulsions (ANE) are a large segment of the explosives market for the mining industry. These emulsions are generally designed to be very stable but when breakdown does occur, removal of the resulting thick, crystallized material can be difficult, hazardous, time consuming and costly. A heavily crystallized emulsion cannot be pumped, so manual removal often becomes necessary. Buildup of semi-solid layers of crystallized emulsion can occur in bulk storage tanks or in truck compartments. In these situations, a manual cleanup involving hazardous confined-space entry and a significant amount of downtime is usually required. Once the crystallized emulsion is removed from the equipment, there is very expensive disposal of the resultant waste via a licensed trade-waste company. A much more desirable solution for dealing with waste emulsion is to completely break the emulsion, allowing the oxidizer and fuel phases to separate into two distinct layers. These layers would then be readily pumpable and could be disposed of much more economically. It may even be possible that the separated oxidizer phase could be repurposed as fertilizer and the fuel phase could be used to manufacture granular ANFO explosives. There are some existing products on the market for breaking emulsion explosives, but these generally need a high degree of mixing into the emulsion to achieve adequate breakdown. The aim of this study was to identify surfactants systems (demulsifiers) capable of effectively breaking a range of waste emulsions with minimized agitation. This paper describes the development and performance testing of novel demulsifier products. The test work involved a comprehensive series of laboratory screening tests, where the demulsifier formulations were optimized. A highly efficient formulation was identified, and field trials were conducted on real world, full-scale waste emulsions. Results will be presented that demonstrate a viable solution for the disposal, and potential re-use, of waste ANE in the explosives industry.