Effects of Multi Heat-Stable Salts on Corrosion in Amine Treating Plants

Corrosion is a major operational problem in amine-treating plants causing significant expenditures each year, Corrosion may become more severe when the amine plants contain process contaminants ? namely heat-stable salts. The heat-stable salts enter the plants with feed-gas streams and makeup-solution, and/or are produced within the plants by reactions of alkanolamine and available carboxylic-acid anions, This work investigated interaction corrosion effects that may exist in amine-treating plants containing a mixture of heat-stable salts, The investigation was experimentally carried out in a 5 kmol/m3 monoethanolamine (MEA) solution containing 0,20 mol/mol carbon dioxide (CO2) loading at 80°C under atmospheric pressure using carbon steel 1018, Six heat-stable salts, including formate, oxalate, bicine, acetate, thiosulfate and chloride, were tested with a series of salt combinations, Potentiodynamic Polarization, Tafel Extrapolation, and Cyclic Polarization were used for revealing corrosion behavior, determining corrosion rate, and examining the pitting tendency, respectively, Results show that thiosulfate induces the most corrosive environment when present either individually or in the form of salt mixtures.