Effect Of Pressure Under Hydrous And Anhydrous Conditions On The Rheological Properties Of Kaolin

The rheological properties of five kaolins, isostatically pressurized at 4 x10 Pa for 10 min in the presence/absence of water, was determined. Under dry conditions, measured viscosity values either decreased or remained the same. After treatment under wet conditions, measured viscosity values were 30-60% higher at high shear and 50-60% higher at low shear. These results correlate with variations in nanomorphology and structural order. Dry compaction degraded kaolinite crystals but wet-pressing appeared to cause an increase in the proportion of euhedral crystallites and a decrease in deformed crystals. Dry compaction decreased the low-defect phase proportion (ldp), but in contrast, the ldp in wet-treated kaolins remained constant or increased. Results show that hydrous pressure treatment produces a change in viscosity of kaolin suspensions, yielding the potential for improving paper coating performance, whereas anhydrous pressure treatment decreased or maintained the viscosity.