Dissolution of zinc shot in electrogalvanizing solutions

"Use of zinc shot feed is a well-established procedure among North American electro-galvanizers. This form of zinc is easy to handle and relatively inexpensive when compared with zinc oxide. This paper reports results on the kinetics of zinc shot dissolution in traditional pure zinc solutions and in electrolytes used for the plating of nickel/zinc alloys. Despite the cementation of minor amounts of nickel in the latter solution, acceptable dissolution rates of the zinc shot can be achieved through proper adjustment of the solution velocity. Under these conditions, the nickel shell produced by cementation is continuously abraded, exposing the underlying zinc.IntroductionThe use of insoluble, noble metal-containing anodes rather than soluble zinc anodes for the operation of high current density electro-galvanizing lines has gained almost universal acceptance. Two major reasons for this trend are:• improved control of the process by virtue of constant inter-electrode distance; and• increased productivity because the operation of the lines does not require the relatively frequent interruptions for replacement of consumed anodes .The results of the principal anode and cathode reactions are, respectively, depletion of the zinc content of the electrolyte and the increase on its acidity;"