Developments of Phosphate Flotation Reagents in China

Most phosphate ores in China are characterized by fine dissemination of the intergrown minerals and high content of carbonates. Therefore, in order to recover phosphorus minerals by flotation, some technological problems must be solved, such as fine particle flotation and separation of phosphate from carbonates. For effective flotation of finely ground phosphate ores and selective separation of phosphorus minerals from carbonates, S-series and L339 modifiers have been developed. A series of combined collectors with improved collector ability and selectivity have been developed and applied in several flotation plants in China. In this paper, CCLS, a combined collector for phosphates and PA-31 and a collector for reverse flotation of carbonates, are described. It has been found that some surfactants added with fatty acids function well in flotation at lower temperature, hence heating pulp in winter may be excluded. It is important for energy savings. The synergy mechanism of these additives in fatty acid flotation is discussed in this paper.