Detonation Behavior of Emulsion Explosives Containing Large Voids

The emulsion explosives show non- ideal detonation behavior, and its detonation velocity can be controled by selecting the size and adjusting the quantity of voids involved. To establish the technology to control the detonation characteristics of the emulsion explosives, some experiments have been carried out using resin balloons of five different sizes ranged from O.OSmm to 2.42mm in the average diameter. Detonation velocities of the emulsion explosives containing resin balloons of different size and quantity were determined for the charge diameter of 20-50mm. The detonation velocity at infinite charge diameter was compared with calculated ideal detonation velocity. The emulsion explosives containing large (0.5mm or larger) balloons showed big discrepancy between the measured and calculated detonation velocities, and the fraction of ammonium nitrate reacted in the reaction zone was estimated to be significantly low. It was shown that the reaction zone length was proportional to the size of voids involved. The critical charge diameter was determined for the emulsion explosives containing different resin balloons at the various explosive densities. It is large for the emulsion explosives containing large voids, and it was shown that the critical diameter is proportional to the distance between the void surfaces, not to the void spacing, the distance between the centers of the voids. The reaction rate of the bulk emulsion matrix seems to be the major factor that affects the critical diameter than the specific surface of voids. Good relationship between the critical diameter and the reaction zone length was observed.