Design of refractories and bindings for modem high-productivity pyrometallurgical furnaces

"Developments in pyrometallurgical technology have led to larger furnaces operating under more intense process conditions. In order to maintain the reliability of these furnaces, which are frequently single-line units, the design of the refractories, cooling systems and bindings has become more critical. Traditional thermal and chemical requirements for the refractory to resist slag attack must still be carefully determined. The larger, modem furnaces have placed a new emphasis on the structural properties of the refractories as well as their thermal properties to suit the extensive cooling systems. Based on operating experience, supported by computer models, the refractories and bindings are designed to work together to accommodate the thermal expansions and contractions in order to minimize permanent furnace growth and the risks of leaks. IntroductionElectric furnaces are used extensively in smelting copper and nickel ores and concentrates. Laterite nickel ores and high-magnesia copper, nickel and platinum sulphide concentrates are smelted virtually exclusively in electric furnaces to accommodate the high melting point of the slags produced. Although a number of smelting processes using oxygen-enriched and/or preheated air have been developed to replace reverberatory furnace smelting of conventional copper and copper-nickel concentrates, (lnco, Noranda, Outokumpu, Mitsubishi) electric matte furnaces remain a strong process alternative for these concentrates, either as the primary smelting vessel or for cleaning the slags produced from these processes.The development of large, high-powered furnaces has been an important factor in the growth of electric smelting technology, as evidenced by the list of operating matte and ferronickel furnaces shown in Table I. Because the compressive forces required to maintain a tight, leak-free furnace increase with furnace dimensions, the selection and design of the furnace refractories, cooling systems and bindings require increased attention."