Damage Mechanism and Toxic Leaching Rule of Coal Gangue Under Multi‑field Coupling Action - Mining, Metallurgy & Exploration (2023)

By introducing the hydrochemical damage variable of coal gangue granular material, this paper analyzed the evolution law of gangue mechanical parameters with hydrochemical damage. By constructing a gangue damage model considering multifield coupling, the damage mechanism of gangue under multi-field coupling was revealed from the microscopical aspect, and the influence law of gangue damage mechanism on the dissolution of toxic substances under multi-field coupling was obtained: the conditions of Test 1 have the greatest influence on the porosity of coal gangue, and the damage of coal gangue is the greatest. Cu, Zn, Cd, and Pb are more easily leached under acidic conditions. The coupling effect of seepage, temperature, and chemical field can promote the formation of secondary voids, change the voids, and form migration paths in coal gangue. The kinetic model of toxic leaching of coal gangue under multi-field coupling can be well characterized by Elovich equation. The release mechanism of heavy metals is mainly manifested as delayed diffusion or dissolution in the early stage, diffusion and dissolution in the middle stage, and depletion in the late stage.