Cyanide Regeneration and Copper Recovery from Cyanidation Tailings

A method has been developed to recover cyanide and copper from cyanidation effluents contaminated with thiocyanate and copper-cyanide complexes. Copper is precipitated as copper thiocyanate or as copper cyanide depending on pH and the concentrations of thiocyanate and cyanide present in the effluent. The copper precipitate presents good dewatering characteristics and can be easily separated from the effluent by thickening and filtration. The solution containing the bulk of the cyanide is then oxidized with ozone to transform the remaining thiocyanate into cyanide. This results in a regenerated solution rich in free cyanide that can be recycled to the cyanidation process. Careful control of the pH of the solution is required. First pH of the effluent is lowered to optimize the precipitation and oxidation stages, then the pH is restored to an alkaline value to regenerate the cyanide solution. Recoveries of over 96% copper are obtained. Free cyanide in the regenerated solution corresponds to up to 160% of the total cyanide contained in the original impure effluent. (The balance being accounted for by the cyanide obtained by the oxidation of thiocyanate). The efficiency of the thiocyanate oxidation stage is 85% to 90%. The method has been demonstrated at bench scale with effluents of various cyanidation plants of northern Quebec. A preliminary economic evaluation indicates that the procedure would be profitable for effluents rich in copper and thiocyanate. This is the case for most barren bleeds of Merrill Crowe and heap leaching operations and also certain CIP tailings of gold ores containing copper impurities. Environmentally the procedure is a better alternative than the current detoxification methods based on the oxidation of cyanide that do not allow for copper recovery and that have difficulties in producing a final effluent with acceptable levels of contaminants such as ammonia, thiocyanate and copper.